Towards resource efficient chemistry: tandem reactions with renewables

被引：194
作者：
Behr, Arno [1 ]
Vorholt, Andreas J. [1 ]
Ostrowski, Karoline A. [1 ]
Seidensticker, Thomas [1 ]
机构：
[1] Tech Univ TU Dortmund, Chair Tech Chem, Dept Biochem & Chem Engn, D-44227 Dortmund, Germany
来源：
GREEN CHEMISTRY | 2014年 / 16卷 / 03期
关键词：
ONE-POT SYNTHESIS; CARBON-DIOXIDE; CROSS-METATHESIS; OLEFIN-METATHESIS; FATTY-ACIDS; NATURAL OILS; CARBOXYLIC-ACIDS; IMPORTANT DERIVATIVES; RUTHENIUM CATALYSTS; ALTERNATIVE CONCEPT;
D O I：
10.1039/c3gc41960f
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
In an economically expanding world new sustainable concepts have to be developed in order to overcome growing problems of resource availability. Merging different "Green principles" is a promising concept in this respect, e. g. the combination of tandem reactions and renewables. This review summarizes the trends in this field and demonstrates advantages and future demands. Four reactions, namely metathesis, hydroformylation, defunctionalisation and isomerisation, have been identified for transforming renewables in tandem reactions. Every reaction yields a reactive intermediate or secures a tailored selectivity in order to use the natural molecular structure of renewables.
引用
收藏
页码：982 / 1006
页数：25
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