Rapid and highly chemoselective biomimetic oxidation of organosulfur compounds with tetrabutylammonium peroxymonosulfate in the presence of manganese meso-tetraphenylporphyrin and imidazole

被引：81
作者：
Iranpoor, N [1 ]
Mohajer, D [1 ]
Rezaeifard, AR [1 ]
机构：
[1] Shiraz Univ, Coll Sci, Dept Chem, Shiraz 71454, Iran
来源：
TETRAHEDRON LETTERS | 2004年 / 45卷 / 19期
关键词：
sulfone; thiosulfonate; tetrabutylammonium peroxy-monosulfate; manganese porphyrin;
D O I：
10.1016/j.tetlet.2004.03.082
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A novel and efficient method is described for the immediate oxidation of different organosulfur compounds using tetra-butylammonium peroxymonosulfate in the presence of manganese meso-tetraphenylporphyrin and imidazole. The method is highly chemoselective and the yields are excellent. (C) 2004 Published by Elsevier Ltd.
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收藏
页码：3811 / 3815
页数：5
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