Design and fabrication of a TiO2/nano-silicon composite visible light photocatalyst

被引:25
作者
Lin, Chun Yu
Fang, Yean Kuen [1 ]
Kuo, Che Hao
Chen, Shih Fang
Lin, Chun-Sheng
Chou, Tse Heng
Lee, Yu-Hua
Lin, Jui-Che
Hwang, Sheng-Beng
机构
[1] Natl Cheng Kung Univ, Dept Elect Engn, Inst Microelect, VLSI Technol Lab, Tainan 70101, Taiwan
[2] Natl Cheng Kung Univ, Dept Phys, Tainan 70101, Taiwan
[3] Natl Cheng Kung Univ, Dept Chem Engn, Tainan 70101, Taiwan
关键词
nano-silicon; TiO2; photocatalyst; methylene blue; super-hydrophilic;
D O I
10.1016/j.apsusc.2006.01.030
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Nano-silicon (nc-Si) was utilized as the charges generator to promote the photocatalytic and super-hydrophilic reactivity of TiO2 film under visible light irradiation. The photocatalytic ability of TiO2/nc-Si composite photocatalyst was evaluated by a set of experiments to photodecompose 100 ppm methylene blue (MB) in aqueous solution. And the super-hydrophilic property was characterized by measuring the water droplet contacts angle, under visible light irradiation in atmospheric air and at room temperature. Under 100 mW/cm(2) visible light irradiation, the droplet contact angles were reduced to 0 degrees within 4 h with nc-Si charge generator. Additionally, the rate constant of MB photo-degradation was promoted 6.6 times. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码:898 / 903
页数:6
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