Synthesis and metal complexation of two vic-dioxime derivatives of calix[4]arenes

被引：11

作者：

Deligoz, H ^{[1
]}

Yilmaz, M ^{[1
]}

机构：

[1] SELCUK UNIV,DEPT CHEM,TR-42079 KONYA,TURKEY

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY | 1997年 / 27卷 / 03期

关键词：

D O I：

10.1080/00945719708000196

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two new vic-dioxime compounds of calix[4]arene and their transition metal complexes were synthesized from 28-[(4-aminobenzyl)oxy]-25,26,27-tribenzoyl-oxycalix[4]arene and amphi-chloroglyoxime or amphi-dichloroglyoxime. The complexes of these compounds with Ni(II), Cu(II) and Co(II) ions were investigated. All of the complexes of these ligands are tetrahedral with a metal-ligand ratio of 1:2. The prepared compounds were characterised based on H-1 NMR and IR spectra as well as elemental analyses.

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页码：391 / 400

页数：10

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