Novel pH- and Temperature-Responsive Methacrylamide Microgels

被引：6

作者：

Perez-Alvarez, Leyre ^{[1
]}

Saez-Martinez, Virginia ^{[1
]}

Hernaez, Estibaliz ^{[1
]}

Katime, Issa ^{[1
]}

机构：

[1] Univ Basque Country, Dept Quim Fis, Fac Ciencia & Tecnol, Grp Nuevos Mat & Espect Supramol, E-48080 Bilbao, Spain

来源：

MACROMOLECULAR CHEMISTRY AND PHYSICS | 2009年 / 210卷 / 13-14期

关键词：

methacrylamide; microgels; pH sensitive; thermoresponsive; PHYSICOCHEMICAL PROPERTIES; N-ISOPROPYLACRYLAMIDE; SENSITIVE MICROGELS; DRUG-DELIVERY; PARTICLES; LATTICES; ACID; COPOLYMERIZATION; POLYVINYLAMIDES; POLYMERIZATION;

D O I：

10.1002/macp.200900058

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A novel transition temperature in MeAM copolymer microgels is reported. Despite the fact that MeAM homopolymers do not show thermosensitive properties, a specific synthetic strategy leads to a thermo-responsive swelling behavior that could be potentially useful in medical and/or industrial applications. The pH of microgels of MeAM copolymerized with 2-aminomethylpyridine and ethylenediamine is reported. The changes in particle sizes, which depend on the nature of the surrounding environment, are recorded by GELS. The relation between copolymer structure and its novel behavior is analyzed by several techniques (H-1 NMR, TGA).

引用

页码：1120 / 1126

页数：7

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