Production of vibrationally excited N2 by electron impact

Energy transfer from electrons to neutral gases and ions is one of the dominant electron cooling processes in the ionosphere, and the role of vibrationally excited N-2 in this is particularly significant. We report here the results from a new calculation of electron energy transfer rates (Q) for vibrational excitation of N-2, as a function of the electron temperature T-c. The present study was motivated by the development of a new cross-section compilation for vibrational excitation processes in N-2 which supercedes those used in the earlier calculations of the electron energy transfer rates. We show that the energy dependence and magnitude of these cross sections, particularly in the region of the well-known (2)Pi(g) resonance in N-2, significantly affect the calculated values of Q. A detailed comparison between the current and previous calculated electron energy transfer rates is made and coefficients are provided so that these rates for transitions from level 0 to levels 1-10 can be calculated for electron temperatures less than 6000 K. (C) 2004 Elsevier Ltd. All rights reserved.