Surface Plasmon response of Pd deposited ZnO/CuO nanostructures with enhanced photocatalytic efficacy towards the degradation of organic pollutants

被引:29
作者
Kumari, Vijaya [1 ]
Yadav, Suprabha [1 ]
Mittal, Anuj [1 ]
Kumari, Kavitha [2 ]
Mari, Bernabe [3 ]
Kumar, Naveen [1 ]
机构
[1] Maharshi Dayanand Univ, Dept Chem, Rohtak, Haryana, India
[2] Deenbandhu Chottu Ram Univ Sci & Technol, Dept Chem, Murthal, Sonepat, India
[3] Univ Politecn Valencia, Dept Fis Aplicada, Inst Disseny Fabricacio Automatitzada, Valencia 46022, Spain
关键词
Nano-composites; Deposition method; Triclopyr; Rhodamine; Degradation; NIR region; HYDROGEN GENERATION; TIO2; NANOCOMPOSITES; PERFORMANCE; OXIDATION; CATALYSTS; EFFICIENT; SILVER;
D O I
10.1016/j.inoche.2020.108241
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Herein, we have synthesized novel noble metal Pd deposited ZnO/CuO (8:1) nano-composites using simple single step deposition method with different weight percentage. The morphological, structural, elemental and optical characteristics of synthesized materials were uncovered by using different techniques such as FESEM, TEM, XRD, XPS and UVDRS. The synthesized materials are highly crystalline in nature. To evaluate the de-gradation efficacy of synthesized nano-composite materials, two organic pollutants; rhodamine B and triclopyr, are taken into account. The complete degradation of RhB and TCP is observed in 20 and 60 min. The nano composite with 2% Pd shows highest efficacy towards the photodegradation of pollutants. The better photo degradation efficacy of synthesized nano-composite materials is attributed to appropriate amount of Pd de-position which helps in shifting the absorption towards NIR region and efficiently reduces the recombination rate of charge carriers.
引用
收藏
页数:9
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[31]   Lauric acid surface modified Co2+-ZnO@SSM composite membrane: Photocatalytic degradation of MB and oil/water separation for removal of organic pollutants [J].
Wu, Qiqi ;
Zhang, Wentao ;
Qu, Chen ;
Yuan, Fei ;
Huang, Yi ;
Chen, Xianfei ;
Zhang, Ruoxi .
APPLIED SURFACE SCIENCE, 2023, 622
[32]   Facile synthesis of Pd nanoparticles dispersed polypyrrole-carbon black/ NiO nanocomposite with enhanced photocatalytic degradation of colored and colorless organic pollutants [J].
Faisal, M. ;
Ahmed, Jahir ;
Jalalah, Mohammed ;
El-Toni, Ahmed Mohamed ;
Labis, Joselito P. ;
Khan, Aslam ;
Harraz, Farid A. .
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2023, 677
[33]   Enhanced selective photocatalytic and sonocatalytic degradation in mixed dye aqueous solution by ZnO/GO nanocomposites: Response surface methodology [J].
Mahdavi, Reza ;
Talesh, S. Siamak Ashraf .
MATERIALS CHEMISTRY AND PHYSICS, 2021, 267 (267)
[34]   Hydroxylamine-enhanced Fe(II)-peroxymonosulfate activation for efficient degradation of organic pollutants: optimization by response surface methodology [J].
Zhang, Kuo ;
Zhang, Ming ;
Zhou, Runjuan ;
Zhou, Ting .
WATER SCIENCE AND TECHNOLOGY, 2022, 86 (04) :834-846
[35]   Self-assembled porphyrin on coral-like ZnO nanoplates: A novel hybrid for enhanced photocatalytic degradation of organic pollutants under simulated sunlight [J].
La, Duc D. ;
Lai, Duy Van ;
Nguyen, D. ;
Nguyen, D. Duc .
CATALYSIS TODAY, 2025, 449
[36]   In situ S-doped ultrathin gC3N4 nanosheets coupled with mixed-dimensional (3D/1D) nanostructures of silver vanadates for enhanced photocatalytic degradation of organic pollutants [J].
Joseph, Subi ;
Abraham, Sinoj ;
Priyanka, Ragam N. ;
Abraham, Thomas ;
Suresh, Arya ;
Mathew, Beena .
NEW JOURNAL OF CHEMISTRY, 2019, 43 (26) :10618-10630
[37]   Peroxymonosulfate enhanced photocatalytic degradation of Reactive Black 5 by ZnO-GAC: Key influencing factors, stability and response surface approach [J].
Liu, Fuzhen ;
Wang, Xue ;
Liu, Zhengzhi ;
Miao, Fei ;
Xu, Yin ;
Zhang, Hui .
SEPARATION AND PURIFICATION TECHNOLOGY, 2021, 279
[38]   A dual surface inorganic molecularly imprinted Bi2WO6-CuO/Ag2O heterostructure with enhanced activity-selectivity towards the photocatalytic degradation of target contaminants [J].
Amiri, Maryam ;
Dashtian, Kheibar ;
Ghaedi, Mehrorang ;
Mosleh, Soleiman .
PHOTOCHEMICAL & PHOTOBIOLOGICAL SCIENCES, 2020, 19 (07) :943-955
[39]   Internal piezoelectric field produced by tri-component (FTO: Sb-ZnO/ MoS2) thin film for enhanced photocatalytic degradation of organic pollutants and antibacterial activity [J].
Masekela, Daniel ;
Hintsho-Mbita, Nomso C. ;
Dlamini, Langelihle N. ;
Yusuf, Tunde L. ;
Mabuba, Nonhlangabezo .
MATERIALS TODAY COMMUNICATIONS, 2024, 38
[40]   ZnO quantum dots decorated 3DOM TiO2 nanocomposites: Symbiose of quantum size effects and photonic structure for highly enhanced photocatalytic degradation of organic pollutants [J].
Zalfani, Meryam ;
van der Schueren, Benoit ;
Mandouani, Mounira ;
Bourguiga, Ramzi ;
Yu, Wen-Bei ;
Wu, Min ;
Deparis, Olivier ;
Li, Yu ;
Su, Bao-Lian .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2016, 199 :187-198