Thermal degradation of α- and β-PbO2 and its relationship to capacity loss

被引:13
作者
Fitas, R [1 ]
Zerroual, L [1 ]
Chelali, N [1 ]
Djellouli, B [1 ]
机构
[1] Univ Ferhat ABBAS, Inst Chim Ind, Lab Energet & Electrochim Solides, Setif 19000, Algeria
关键词
capacity loss; alpha-PbO2; beta-PbO2; thermal degradation;
D O I
10.1016/S0378-7753(99)00382-1
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The thermal degradation of alpha and beta PbO2 and its relationship to capacity loss was studied using galvanostatic discharge and voltamperometry. The results clearly demonstrate the dramatic effect of the thermal treatment on the capacity of the PAM. The variation of proton diffusion with temperature was determined for both alpha- and beta-PbO2. The two forms of PbO2 exhibit different behaviour with regard to water loss. (C) 2000 Elsevier Science S.A. AU rights reserved.
引用
收藏
页码:56 / 58
页数:3
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