Preparation of polymer-dispersed liquid crystal doped with indium tin oxide nanoparticles

被引:26
作者
Zhang, Yi [1 ]
Yang, Jie [1 ]
Zhou, Le [2 ]
Gao, Yanzi [2 ]
Hai, Mingtan [1 ]
Zhang, Lanying [2 ]
Li, Fasheng [4 ]
Zhou, Guofu [5 ]
Li, Xiaoran [6 ]
Zhang, Cuihong [3 ]
Yang, Zhou [1 ]
Zhu, Siquan [7 ]
Yang, Huai [2 ]
机构
[1] Univ Sci & Technol Beijing, Sch Mat Sci & Engn, Dept Mat Phys & Chem, Beijing, Peoples R China
[2] Peking Univ, Dept Mat Sci & Engn, Coll Engn, Beijing, Peoples R China
[3] Xijing Univ, Sch Sci, Key Lab Organ Polymer Photoelect Mat, Xian, Shaanxi, Peoples R China
[4] Dalian Med Univ, Coll Med Lab, Dalian, Liaoning, Peoples R China
[5] South China Normal Univ, South China Acad Adv Optoelect, Inst Elect Paper Inst, Guangzhou, Guangdong, Peoples R China
[6] Shenzhen Optoelect Tech Co Ltd, Shenzhen, Peoples R China
[7] CMU, Beijing Tongren Hosp, Beijing, Peoples R China
基金
中国国家自然科学基金;
关键词
Polymer-dispersedliquid crystal; ITO NPs; thiol-acrylate; electro-opticalproperties; anti-infraredradiation; LIGHT-SCATTERING PROPERTIES; ELECTROOPTICAL PROPERTIES; FILMS; MATRIX; COMPOSITES; DROPLETS; MICROSTRUCTURE; MORPHOLOGY; DYNAMICS; MONOMERS;
D O I
10.1080/02678292.2017.1408864
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
To study polymer-dispersed liquid crystal (PDLC) films doped with indium tin oxide (ITO) nanoparticles (NPs), samples were prepared by ultraviolet-initiated polymerisation based on the thiol-acrylate system. Owing to the interaction between PDLC system and ITO NPs, the content and the size of ITO NPs are the main determinants to the microstructure which plays an essential role on the electro-optical and anti-infrared properties of the PDLC films. In the polymer matrix, a novel microstructure consisting of a dense surface, micron-sized meshes and submicron meshes is found to benefit the better performances of the low driven voltage (20.7V), the relatively high contrast ratio (8.3) and the lowest transmittance(500-2500nm) on average at about 3.55% with maximum of merely 7.6%. Thus, it lays a solid foundation for the further investigations on the microstructure and the performance of the PDLC films. Meanwhile, it is proved that the PDLC film, improved performance through doping ITO NPs, is promising to be a superior choice in the field of energy-saving. [GRAPHICS] .
引用
收藏
页码:1068 / 1077
页数:10
相关论文
共 35 条
[1]   Effects of Ultraviolet-curing conditions on the electro-optical behavior of polymer dispersed liquid crystal films [J].
Abdoune, FZ ;
Benkhaled, L ;
Coqueret, X ;
Maschke, U ;
Mechernene, L .
MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 2004, 422 :163-172
[2]   PDLC composites based on polyvinyl boric acid matrix - a promising pathway towards biomedical engineering [J].
Ailincai, Daniela ;
Farcau, Cosmin ;
Paslaru, Elena ;
Marin, Luminita .
LIQUID CRYSTALS, 2016, 43 (13-15) :1973-1985
[3]   Morphology and electro-optic properties of polymer-dispersed liquid-crystal films [J].
Amundson, K ;
vanBlaaderen, A ;
Wiltzius, P .
PHYSICAL REVIEW E, 1997, 55 (02) :1646-1654
[4]   Effects of tin on IR reflectivity, thermal emissivity, Hall mobility and plasma wavelength of sol-gel indium tin oxide films on glass [J].
Biswas, PK ;
De, A ;
Pramanik, NC ;
Chakraborty, PK ;
Ortner, K ;
Hock, V ;
Korder, S .
MATERIALS LETTERS, 2003, 57 (15) :2326-2332
[5]   Polymerization-induced phase separation .1. Conversion-phase diagrams [J].
Boots, HMJ ;
Kloosterboer, JG ;
Serbutoviez, C ;
Touwslager, FJ .
MACROMOLECULES, 1996, 29 (24) :7683-7689
[6]   Dependence of the morphology of polymer dispersed liquid crystals on the UV polymerization process [J].
Carter, SA ;
LeGrange, JD ;
White, W ;
Boo, J ;
Wiltzius, P .
JOURNAL OF APPLIED PHYSICS, 1997, 81 (09) :5992-5999
[7]   The n-alcohols liquid doping effect on the twisted nematic liquid crystals [J].
Chen, Jun-Wei ;
Wang, Chao-Ran ;
Chou, Tsu-Ruey ;
Chen, Wei-Ting ;
Chao, Chih-Yu .
DISPLAYS, 2016, 45 :39-43
[8]   Effective medium theory of light scattering in polymer dispersed liquid crystal films [J].
Cox, SJ ;
Reshetnyak, VY ;
Sluckin, TJ .
JOURNAL OF PHYSICS D-APPLIED PHYSICS, 1998, 31 (14) :1611-1625
[9]   POLYMER DISPERSED LIQUID-CRYSTALS FOR DISPLAY APPLICATION [J].
DOANE, JW ;
GOLEMME, A ;
WEST, JL ;
WHITEHEAD, JB ;
WU, BG .
MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1988, 165 :511-532
[10]   REORIENTATION DYNAMICS OF POLYMER DISPERSED NEMATIC LIQUID-CRYSTAL FILMS [J].
DRZAIC, PS .
LIQUID CRYSTALS, 1988, 3 (11) :1543-1559