Construction of two novel coordination polymers from a V-shaped bisimidazole ligand: Synthesis, characterization and properties

被引:12
作者
Guo, Xianmin [1 ]
Yan, Yongnian [1 ]
Guo, Huadong [1 ]
Wang, Nan [1 ]
Qi, Yanjuan [1 ]
机构
[1] Changchun Normal Univ, Dept Chem, Changchun 130032, Peoples R China
关键词
Coordination polymers; Helice; Polyrotaxane; Luminescence; METAL-ORGANIC FRAMEWORKS; CRYSTAL-STRUCTURES; TRANSFORMATION; IMIDAZOLE; NETWORKS;
D O I
10.1016/j.inoche.2015.12.020
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Two novel coordination polymers, [Cd-2(cdc)(2)(bmis)(2)] (1) and [Zn-6(cdc)(4)(OH)(4)(bmis)(4)]center dot 2H(2)O center dot 4DMF (2) (bmis = bis(4-(2'-methylimidazol-ylphenyl)sulfone, H(2)cdc = 1,4-cyclohexanedicarboxylic acid), have been synthesized and structurally characterized. Compound 1 features an interesting usf net presenting the alternate arrangement of the single- and triple-stranded helices. Compound 2 exhibits an unusual two-fold interpenetrating polyrotaxane motif composed of two interlocked sets of identical pcu nets. In addition, their photoluminescent properties have also been evaluated. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码:59 / 62
页数:4
相关论文
共 23 条
[1]   Luminescent metal-organic frameworks [J].
Allendorf, M. D. ;
Bauer, C. A. ;
Bhakta, R. K. ;
Houk, R. J. T. .
CHEMICAL SOCIETY REVIEWS, 2009, 38 (05) :1330-1352
[2]   Polycatenation, polythreading and polyknotting in coordination network chemistry [J].
Carlucci, L ;
Ciani, G ;
Proserpio, DM .
COORDINATION CHEMISTRY REVIEWS, 2003, 246 (1-2) :247-289
[3]   Tunable emission based on lanthanide(III) metal-organic frameworks: an alternative approach to white light [J].
Dang, Song ;
Zhang, Jian-Han ;
Sun, Zhong-Ming .
JOURNAL OF MATERIALS CHEMISTRY, 2012, 22 (18) :8868-8873
[4]   Flexible dicarboxylate based pillar-layer metal organic frameworks: differences in structure and porosity by tuning the pyridyl based N, N′ linkers [J].
Dey, Rajdip ;
Bhattacharya, Biswajit ;
Pachfule, Pradip ;
Banerjee, Rahul ;
Ghoshal, Debajyoti .
CRYSTENGCOMM, 2014, 16 (11) :2305-2316
[5]   Three coordination polymers with helical chains based on methylenediisophthalic acid (H4MDIP) [J].
Duan, Xianying ;
Cheng, Xian ;
Lin, Jianguo ;
Zang, Shuangquan ;
Li, Yizhi ;
Zhu, Chengjian ;
Meng, Qingjin .
CRYSTENGCOMM, 2008, 10 (06) :706-714
[6]   Entangled metal-organic frameworks modulated by N-donor ligands of different conformations [J].
Guo, Hua-Dong ;
Qiu, Dong-Fang ;
Guo, Xian-Min ;
Zheng, Guo-Li ;
Wang, Xiao ;
Dang, Song ;
Zhang, Hong-Jie .
CRYSTENGCOMM, 2009, 11 (11) :2425-2430
[7]   Solvent-controlled three families of Zn(II) coordination compounds: synthesis, crystal structure, solvent-induced structural transformation, supramolecular isomerism and photoluminescence [J].
Han, Lu-Lu ;
Hu, Tuo-Ping ;
Mei, Kai ;
Guo, Zhi-Min ;
Yin, Chen ;
Wang, Ya-Xin ;
Zheng, Jun ;
Wang, Xing-Po ;
Sun, Di .
DALTON TRANSACTIONS, 2015, 44 (13) :6052-6061
[8]   A rod packing microporous metal-organic framework: unprecedented ukv topology, high sorption selectivity and affinity for CO2 [J].
Hou, Lei ;
Shi, Wen-Juan ;
Wang, Yao-Yu ;
Guo, Ying ;
Jin, Chen ;
Shi, Qi-Zhen .
CHEMICAL COMMUNICATIONS, 2011, 47 (19) :5464-5466
[9]   Metal-Organic Frameworks for Separations [J].
Li, Jian-Rong ;
Sculley, Julian ;
Zhou, Hong-Cai .
CHEMICAL REVIEWS, 2012, 112 (02) :869-932
[10]   Metal-organic frameworks based on flexible ligands (FL-MOFs): structures and applications [J].
Lin, Zu-Jin ;
Lu, Jian ;
Hong, Maochun ;
Cao, Rong .
CHEMICAL SOCIETY REVIEWS, 2014, 43 (16) :5867-5895