Recyclable Hypervalent Iodine Reagents in Modern Organic Synthesis

被引：20

作者：

Rimi ^{[1
]}

Soni, Sakshi ^{[1
]}

Uttam, Bhawna ^{[1
]}

China, Hideyasu ^{[2
]}

Dohi, Toshifumi ^{[3
]}

Zhdankin, Viktor V. ^{[4
]}

Kumar, Ravi ^{[1
]}

机构：

[1] JC Bose Univ Sci & Technol, Dept Chem, YMCA,NH-2,Sect-6,Mathura Rd, Faridabad 121006, Haryana, India

[2] Nagahama Inst Bio Sci & Technol, Dept Med Biosci, Tamuracho Nagahama shi, Shiga 5260829, Japan

[3] Ritsumeikan Univ, Coll Pharmaceut Sci, 1-1-1 Nojihigashi, Shiga 5258577, Japan

[4] Univ Minnesota Duluth, Dept Chem & Biochem, Univ Dr 126 HCAMS, Duluth, MN 55812 USA

来源：

SYNTHESIS-STUTTGART | 2022年 / 54卷 / 12期

基金：

日本科学技术振兴机构; 日本学术振兴会; 美国国家科学基金会;

关键词：

hypervalent iodine; recyclable reagents; polymer-supported; non-polymeric; ionic-liquid-supported; MOF hybrid; SUPPORTED IBX-AMIDE; HIGHLY SELECTIVE OXIDATION; FLUOROUS ALKYL IODIDES; M-IODOSYLBENZOIC ACID; IONIC-LIQUID; FACILE PREPARATION; BIS(TRIFLUOROACETATE) ADDUCTS; IODO-FUNCTIONALIZATION; ALPHA-TOSYLOXYLATION; EFFICIENT OXIDATION;

D O I：

10.1055/s-0041-1737909

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Hypervalent iodine (HVI) reagents have gained much attention as versatile oxidants because of their low toxicity, mild reactivity, easy handling, and availability. Despite their unique reactivity and other advantageous properties, stoichiometric HVI reagents are associated with the disadvantage of generating non-recyclable iodoarenes as waste/co-products. To overcome these drawbacks, the syntheses and utilization of various recyclable hypervalent iodine reagents have been established in recent years. This review summarizes the development of various recyclable non-polymeric, polymer-supported, ionic-liquid-supported, and metal organic framework (MOF)-hybridized HVI reagents. 1 Introduction 2 Polymer-Supported Hypervalent Iodine Reagents 2.1 Polymer-Supported Hypervalent Iodine(III) Reagents 2.2 Polymer-Supported Hypervalent Iodine(V) Reagents 3 Non-Polymeric Recyclable Hypervalent Iodine Reagents 3.1 Non-Polymeric Recyclable Hypervalent Iodine(III) Reagents 3.2 Recyclable Non-Polymeric Hypervalent Iodine(V) Reagents 3.3 Fluorous Hypervalent Iodine Reagents 4 Ionic-Liquid/Ion-Supported Hypervalent Iodine Reagents 5 Metal Organic Framework (MOF)-Hybridized Hypervalent Iodine Reagents 6 Conclusion. © 2022 Georg Thieme Verlag. All rights reserved.

引用

页码：2731 / 2748

页数：18

共 145 条

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