Palladium-Catalyzed Hydrophosphonylation of Alkenes with Dialkyl H-Phosphonates

被引：15

作者：

Candy, Mathieu ^{[1
]}

Rousseaux, Sophie A. L. ^{[1
]}

Roman, Alberto Cirugeda San ^{[1
]}

Szymczyk, Monika ^{[1
,2
]}

Kafarski, Pawel ^{[2
]}

Leclerc, Eric ^{[1
]}

Vrancken, Emmanuel ^{[1
]}

Campagne, Jean-Marc ^{[1
]}

机构：

[1] ENSCM, CNRS, Inst Charles Gerhardt, UMR 5253,UM2,UM1, F-34296 Montpellier 5, France

[2] Wroclaw Univ Technol, Fac Chem, Dept Bioorgan Chem, PL-50370 Wroclaw, Poland

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2014年 / 356卷 / 11-12期

关键词：

acyclic dialkyl H-phosphonates; alkenes; hydrophosphonylation; palladium catalysis; regioselectivity; COUPLING REACTIONS; HYDROPHOSPHORYLATION; HYDROPHOSPHINYLATION; EFFICIENT;

D O I：

10.1002/adsc.201400190

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The palladium-catalyzed hydrophosphonylation of alkenes with previously unreactive acyclic dialkyl H-phosphonates has been developed. A catalyst system based on palladium/DavePhos or palladium/SPhos enables the transformation of various alkenes to phosphonates in moderate to good yields and with excellent levels of regioselectivity. Hydrophosphonylations with internal, disubstituted and/or unactivated alkenes are also reported.

引用

页码：2703 / 2708

页数：6

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