Synergetic effect of Cu-Pt bimetallic cocatalyst on SrTiO3 for efficient photocatalytic hydrogen production from water

被引:18
作者
Qin, Lixia [1 ]
Si, Guofeng [1 ]
Li, Xiangqing [1 ]
Kang, Shi-Zhao [1 ]
机构
[1] Shanghai Inst Technol, Sch Chem & Environm Engn, Shanghai 201418, Peoples R China
来源
RSC ADVANCES | 2015年 / 5卷 / 124期
基金
中国国家自然科学基金;
关键词
VISIBLE-LIGHT; EVOLUTION REACTION; NANOPARTICLES; CATALYSTS; NANOSHEETS; OXIDATION; TIO2; CO; GRAPHENE;
D O I
10.1039/c5ra22757g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Herein, a series of novel SrTiO3 (STO) based photocatalysts loaded with Cu-Pt bimetallic co-catalysts have been synthesized through a simple photodeposition process. This photocatalyst of STO/Cu-Pt displayed enhanced photocatalytic activity for hydrogen generation from water in the presence of methanol as a sacrificial reagent. Moreover, the hydrogen generation efficiency over the STO/Cu95-Pt5 photocatalyst was about 2.79 and 1.76 times of STO/Cu100-Pt0 and STO/Cu0-Pt100, respectively. Thus, this Cu-Pt synergetic cocatalyst presents an inexpensive and high efficiency cocatalyst to achieve efficient hydrogen evolution from water.
引用
收藏
页码:102593 / 102598
页数:6
相关论文
共 36 条
  • [1] A visible light responsive rhodium and antimony-codoped SrTiO3 powdered photocatalyst loaded with an IrO2 cocatalyst for solar water splitting
    Asai, Rikako
    Nemoto, Hiroaki
    Jia, Qingxin
    Saito, Kenji
    Iwase, Akihide
    Kudo, Akihiko
    [J]. CHEMICAL COMMUNICATIONS, 2014, 50 (19) : 2543 - 2546
  • [2] Detection of Glucose Based on Bimetallic PtCu Nanochains Modified Electrodes
    Cao, Xia
    Wang, Ning
    Jia, Shu
    Shao, Yuanhua
    [J]. ANALYTICAL CHEMISTRY, 2013, 85 (10) : 5040 - 5046
  • [3] Controllable synthesis of supported Cu-M (M =Pt, Pd, Ru, Rh) bimetal nanocatalysts and their catalytic performances
    Chen, Sha
    Zhang, Hongye
    Wu, Lingyan
    Zhao, Yanfei
    Huang, Changliang
    Ge, Maofa
    Liu, Zhimin
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 2012, 22 (18) : 9117 - 9122
  • [4] Size dependent study of MeOH decomposition over size-selected pt nanoparticles synthesized via micelle encapsulation
    Croy, Jason R.
    Mostafa, Simon
    Liu, Jing
    Sohn, Yong-Ho
    Roldan Cuenya, Beatriz
    [J]. CATALYSIS LETTERS, 2007, 118 (1-2) : 1 - 7
  • [5] Preparation, characterization and application of novel conductive NiO-CdO nanofibers with dislocation feature
    Ding, Yu
    Wang, Ying
    Zhang, LiChun
    Zhang, Heng
    Lei, Yu
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 2012, 22 (03) : 980 - 986
  • [6] ELECTROCHEMICAL PHOTOLYSIS OF WATER AT A SEMICONDUCTOR ELECTRODE
    FUJISHIMA, A
    HONDA, K
    [J]. NATURE, 1972, 238 (5358) : 37 - +
  • [7] Review of catalytic supercritical water gasification for hydrogen production from biomass
    Guo, Y.
    Wang, S. Z.
    Xu, D. H.
    Gong, Y. M.
    Ma, H. H.
    Tang, X. Y.
    [J]. RENEWABLE & SUSTAINABLE ENERGY REVIEWS, 2010, 14 (01) : 334 - 343
  • [8] Study on the hydrogenation of p-chloronitrobenzene over carbon nanotubes supported platinum catalysts modified by Mn, Fe, Co, Ni and Cu
    Han, Xiao Xiang
    Chen, Qing
    Zhou, Ren Xian
    [J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2007, 277 (1-2) : 210 - 214
  • [9] Recent progress in synergistic catalysis over heterometallic nanoparticles
    Jiang, Hai-Long
    Xu, Qiang
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 2011, 21 (36) : 13705 - 13725
  • [10] Synergistic Catalysis of Au@Ag Core-Shell Nanoparticles Stabilized on Metal-Organic Framework
    Jiang, Hai-Long
    Akita, Tomoki
    Ishida, Tamao
    Haruta, Masatake
    Xu, Qiang
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (05) : 1304 - 1306