Preparation and balanced mechanical properties of solid and foamed isotactic polypropylene/SEBS composites

被引:12
作者
Zhang, Xiaoli [1 ]
Sun, Baojia [1 ,2 ]
Yuan, Guoyuan [3 ]
Zhang, Shixun [1 ]
Ji, Youxin [1 ]
Liu, Baochen [1 ]
Zhang, Mingxin [1 ]
Yang, Yang [1 ]
Chen, Jingbo [1 ]
机构
[1] Zhengzhou Univ, Natl Engn Res Ctr Adv Polymer Proc Technol, Sch Mat Sci & Engn, Zhengzhou 450001, Peoples R China
[2] Xiamen Jinyue Electroacoust Co Ltd, Mould Workshop, Xiamen, Peoples R China
[3] Zhengzhou Yutong Bus Co Ltd, Prod Engn Dept, Zhengzhou, Peoples R China
基金
中国国家自然科学基金;
关键词
foams; mechanical properties; molding; morphology; thermal properties; BETA-NUCLEATING AGENTS; FOAMING BEHAVIOR; TOUGHNESS REINFORCEMENT; RHEOLOGICAL PROPERTIES; FRACTURE-TOUGHNESS; IMPACT STRENGTH; MORPHOLOGY; BLENDS; CRYSTALLIZATION; NANOPARTICLES;
D O I
10.1002/app.50342
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
This study presents a self-designed foaming apparatus and routes to manufacture foamed isotactic polypropylene (iPP) blends with uniform and dense cells, using styrene-ethylene-butadiene-styrene (SEBS) block copolymer as toughening additive. The addition of SEBS can clearly enhance the impact strength of solid iPP, iPP blends with a 20 wt% SEBS has obtained high notched impact strength of 75 kJ/m(2), which is ca. 16 times larger than that of neat iPP. Relatively fine microcellular iPP-SEBS foams with the average cell size of several micrometers, and the cell density of 10(9) cells/cm(3) were fabricated using a batch foaming procedure. Moreover, using our self-designed mold and compression foaming method, iPP-SEBS foams with balanced mechanical properties were produced. With the increasing of SEBS, tensile strength and flexural strength were slightly decreased, but the impact strength was increased clearly. The balanced mechanical properties between stiffness and toughness were achieved after compression foaming.
引用
收藏
页数:16
相关论文
共 58 条
[1]   A facile method to increase the charge storage capability of polymer nanocomposites [J].
Ameli, Aboutaleb ;
Wang, Sai ;
Kazemi, Yasamin ;
Park, Chul B. ;
Poetschke, Petra .
NANO ENERGY, 2015, 15 :54-65
[2]   Tensile and impact properties of microcellular isotactic polypropylene (PP) foams obtained by supercritical carbon dioxide [J].
Bao, Jin-Biao ;
Nyantakyi, Alex, Jr. ;
Weng, Geng-Sheng ;
Wang, Jia ;
Fang, Yu-Wei ;
Hu, Guo-Hua .
JOURNAL OF SUPERCRITICAL FLUIDS, 2016, 111 :63-73
[3]   Simultaneous improvement of strength and toughness in fiber reinforced isotactic polypropylene composites by shear flow and a β-nucleating agent [J].
Chen, Yan-Hui ;
Huang, Zhang-Yong ;
Li, Zhong-Ming ;
Tang, Jian-Hua ;
Hsiao, Benjamin S. .
RSC ADVANCES, 2014, 4 (28) :14766-14776
[4]   Great toughness reinforcement of isotactic polypropylene/elastomer blends with quasi-cocontinuous phase morphology by traces of β-nucleating agents and carbon nanotubes [J].
Chen, Yanhui ;
Wu, Zhiqiang ;
Fan, Qian ;
Yang, Song ;
Song, Erchao ;
Zhang, Qiuyu .
COMPOSITES SCIENCE AND TECHNOLOGY, 2018, 167 :277-284
[5]   Unexpected Strength and Toughness Reinforcement of the Injection-Molded Isotactic Polypropylene Parts with Oriented β-Crystals [J].
Chen, Yanhui ;
Bo, Xu ;
Yang, Song ;
Yang, Haoqing ;
Lawson, Tom ;
Wu, Zhiqiang ;
Zhang, Qiuyu ;
Li, Zhongming .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2017, 56 (48) :14252-14262
[6]   Foaming behavior of microcellular foam polypropylene/modified nano calcium carbonate composites [J].
Ding, Jie ;
Shangguan, Junnan ;
Ma, Weihua ;
Zhong, Qin .
JOURNAL OF APPLIED POLYMER SCIENCE, 2013, 128 (06) :3639-3651
[7]   Effect of nano-Calcium Carbonate on microcellular foaming of polypropylene [J].
Ding, Jie ;
Ma, Weihua ;
Song, Fujiao ;
Zhong, Qin .
JOURNAL OF MATERIALS SCIENCE, 2013, 48 (06) :2504-2511
[8]   Evaluation of polypropylene/clay nanocomposite foamability based on their morphological and rheological aspects [J].
Dutta, Anindya ;
Sankarpandi, Sabapathy ;
Ghosh, Anup K. .
JOURNAL OF CELLULAR PLASTICS, 2018, 54 (05) :829-850
[9]   Great improvement of low-temperature impact resistance of isotactic polypropylene/ethylene propylene diene monomer rubber blends by traces of carbon nanotubes and β-nucleating agents [J].
Fan, Qian ;
Zhang, Jinghan ;
Wu, Zhiqiang ;
Yang, Song ;
Chen, Yanhui ;
Lu, Ying ;
Zhang, Qiuyu .
POLYMERS FOR ADVANCED TECHNOLOGIES, 2020, 31 (03) :508-519
[10]   Optimizing the balance between impact strength and stiffness in polypropylene/elastomer blends by incorporation of a nucleating agent [J].
Fanegas, N. ;
Gomez, M. A. ;
Jimenez, I. ;
Marco, C. ;
Garcia-Martinez, J. M. ;
Ellis, G. .
POLYMER ENGINEERING AND SCIENCE, 2008, 48 (01) :80-87