Improved separation of Ce, La, and Nd from a concentrate of rare-earth hydroxide via fractional precipitation

被引:1
作者
Haritsah, I [1 ]
Adi, W. A. [2 ]
Purwani, M., V [3 ]
Manaf, A. [1 ]
机构
[1] Univ Indonesia, Fac Math & Nat Sci FMIPA, Dept Phys, Mat Sci Grad Program, Depok 16424, Indonesia
[2] Natl Nucl Energy Agcy BATAN, Ctr Sci & Technol Adv Mat, Kawasan Puspiptek Serpon 15314, Banten, Indonesia
[3] Natl Nucl Energy Agcy BATAN, Ctr Sci & Technol Accelerator, Jl Babarsari Caturtunggal, Sleman 55281, Yogyakarta, Indonesia
来源
2ND INTERNATIONAL CONFERENCE ON CURRENT PROGRESS IN FUNCTIONAL MATERIALS 2017 | 2019年 / 496卷
关键词
SOLVENT-EXTRACTION; THORIUM; RECOVERY; URANIUM; TH(IV);
D O I
10.1088/1757-899X/496/1/012013
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
In this report, we describe the selective and effective separation of Ce, La, and Nd rare-earth (RE) elements from the concentrate of a RE hydroxide (REOH) feedstock. The separation steps included dissolving the feedstock into a nitric acid solution and oxidizing the solution with potassium bromate (KBrO3) as an oxidizing agent to enable precipitation under the addition of sodium hydroxide (NaOH). The yellow precipitates consisted of a concentrate of Ce precipitates, and the filtrate contained La and Nd. The adjustment of the pH of the filtrate to 8.5 with ammonia solution led to the precipitation of Nd and an La concentrate in the filtrate. The developed method was demonstrated to be selective and adequate for the qualification separation of Ce, La, and Nd. This study demonstrates the identification and analysis of REOH from PTBGN-BATAN, Indonesia, and can be used as a reference for further processing at both the laboratory and industrial scale.
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页数:7
相关论文
共 17 条
[1]   Towards zero-waste valorisation of rare-earth-containing industrial process residues: a critical review [J].
Binnemans, Koen ;
Jones, Peter Tom ;
Blanpain, Bart ;
Van Gerven, Tom ;
Pontikes, Yiannis .
JOURNAL OF CLEANER PRODUCTION, 2015, 99 :17-38
[2]  
Biswas S, 2015, THERM EN C OCT 12 15
[3]   Highly Luminescent Self-Organized Sub-2-nm EuOF Nanowires [J].
Du, Ya-Ping ;
Zhang, Ya-Wen ;
Yan, Zheng-Guang ;
Sun, Ling-Dong ;
Yan, Chun-Hua .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (45) :16364-+
[4]   Extraction of uranium, thorium and lanthanides using Cyanex-923: Their separations and recovery from monazite [J].
Gupta, B ;
Malik, P ;
Deep, A .
JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY, 2002, 251 (03) :451-456
[5]  
Li D., 1987, Chin. J. Appl. Chem., V4, P36
[6]   Selective extraction and separation of thorium from rare earths by a phosphorodiamidate extractant [J].
Lu, Youcai ;
Wei, Haiqin ;
Zhang, Zhifeng ;
Li, Yanling ;
Wu, Guolong ;
Liao, Wuping .
HYDROMETALLURGY, 2016, 163 :192-197
[7]   Extraction of Th(IV) with tributyl phosphate from aqueous HCl solutions containing sodium, calcium, or aluminum chloride [J].
Maiorov, V. G. ;
Nikolaev, A. I. .
RUSSIAN JOURNAL OF APPLIED CHEMISTRY, 2006, 79 (07) :1196-1199
[8]   Recovery of rare earth elements, uranium, and thorium from monazite concentrate by supercritical fluid extraction [J].
Samsonov M.D. ;
Trofimov T.I. ;
Kulyako Y.M. ;
Vinokurov S.E. ;
Malikov D.A. ;
Batorshin G.S. ;
Myasoedov B.F. .
Radiochemistry, 2015, 57 (04) :343-347
[9]  
Shen B G, 2011, ADV MATER, V21, P4545
[10]  
Singh DK, 2001, J RADIOANAL NUCL CH, V250, P123