Imidazoline derivative with four imidazole reaction centers as an efficient corrosion inhibitor for anti-CO2 corrosion

被引:21
作者
He, Yi [1 ]
Zhou, Yanqiu [2 ,3 ]
Yang, Ranran [2 ,3 ]
Ma, Lan [2 ,3 ]
Chen, Zhao [2 ,3 ]
机构
[1] Southwest Petr Univ, State Key Lab Oil & Gas Reservoir Geol & Exploita, Chengdu 610500, Sichuan, Peoples R China
[2] Southwest Petr Univ, Sch Chem & Chem Engn, Chengdu 610500, Sichuan, Peoples R China
[3] Southwest Petr Univ, Oil & Gas Field Appl Chem Key Lab Sichuan Prov, Chengdu 610500, Sichuan, Peoples R China
关键词
MILD-STEEL CORROSION; CO2; CORROSION; ADSORPTION PROCESSES; CARBON-STEEL; IRON; TEMPERATURE; MECHANISM; MEDIA; FILM;
D O I
10.1134/S1070427215070149
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Starting from ethylenediamine as the center of the molecule, and terminated by the four peripheral imidazole rings, a dendric derivative with tetra-imidazoline (DDTI) was synthesized. The results of weight loss method showed the inhibition efficiency of DDTI could approximately reach up to 98.29% when the inhibitor dosage was 400 mg L-1. Meanwhile, referring to the potentiodynamic polarization test, DDTI could be classified as a mixed-type inhibitor. What's more, both electrochemical impedance spectroscopy (EIS) and scanning electron microscope (SEM) illustrated that the adsorption between the inhibitors and metal surface was the crucial reason for the high efficiency. Meanwhile, it is interesting that the compact, dendrimer-like and multilayer ed inhibitor films covering on the metal surface regularly acted as the main reason for prominent performance.
引用
收藏
页码:1192 / 1200
页数:9
相关论文
共 36 条
[1]   Adsorption of 3-(4-amino-2-methyl-5-pyrimidyl methyl)-4-methyl thiazolium chloride on mild steel [J].
Abiola, Olusegun K. .
CORROSION SCIENCE, 2006, 48 (10) :3078-3090
[2]   Bis (benzimidazol-2-yl) disulphide: An efficient water soluble inhibitor for corrosion of mild steel in acid media [J].
Ahamad, Ishtiaque ;
Quraishi, M. A. .
CORROSION SCIENCE, 2009, 51 (09) :2006-2013
[3]   2-HYDRAZINO-6-METHYL-BENZOTHIAZOLE AS AN EFFECTIVE INHIBITOR FOR THE CORROSION OF MILD-STEEL IN ACIDIC SOLUTIONS [J].
AJMAL, M ;
MIDEEN, AS ;
QURAISHI, MA .
CORROSION SCIENCE, 1994, 36 (01) :79-84
[4]   Bis-Schiff bases of isatin as new and environmentally benign corrosion inhibitor for mild steel [J].
Ansari, K. R. ;
Quraishi, M. A. .
JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 2014, 20 (05) :2819-2829
[5]   Thermodynamic characterization of metal dissolution and inhibitor adsorption processes in mild steel/2,5-bis(n-thienyl)-1,3,4-thiadiazoles/hydrochloric acid system [J].
Bentiss, F ;
Lebrini, M ;
Lagrenée, M .
CORROSION SCIENCE, 2005, 47 (12) :2915-2931
[6]   Corrosion inhibition of mild steel in acidic media using newly synthesized heterocyclic organic molecules [J].
Fekry, A. M. ;
Ameer, M. A. .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2010, 35 (14) :7641-7651
[7]   Inhibition properties and adsorption behavior of imidazole and 2-phenyl-2-imidazoline on AA5052 in 1.0 M HCl solution [J].
He, Xinkuai ;
Jiang, Yumei ;
Li, Chen ;
Wang, Weichun ;
Hou, Bailong ;
Wu, Luye .
CORROSION SCIENCE, 2014, 83 :124-136
[8]   Heptadecyl-tailed mono- and bis-imidazolines: A study of the newly synthesized compounds on the inhibition of mild steel corrosion in a carbon dioxide-saturated saline medium [J].
Jawich, Mohammed W. S. ;
Oweimreen, G. A. ;
Ali, Shaikh A. .
CORROSION SCIENCE, 2012, 65 :104-112
[9]  
Ju H., 2012, ADV MAT RES, P184
[10]  
Ju H., 2012, ADV MAT RES, P562