Electrical characteristics of organic/inorganic Pt(II) complex/p-Si semiconductor contacts

被引:17
作者
Imer, A. Gencer [1 ]
Temirci, C. [1 ]
Gulcan, M. [2 ]
Sonmez, M. [3 ]
机构
[1] Yuzuncu Yil Univ, Fac Sci, Dept Phys, TR-65080 Van, Turkey
[2] Yuzuncu Yil Univ, Fac Sci, Dept Chem, TR-65080 Van, Turkey
[3] Gaziantep Univ, Fac Sci & Arts, Dept Chem, TR-27310 Gaziantep, Turkey
关键词
Contact; Organic; Rectifier; Schottky; Diode; NONPOLYMERIC ORGANIC-COMPOUND; SCHOTTKY-BARRIER; ELECTRONIC-PROPERTIES; PHOTOVOLTAIC PROPERTIES; DIODE; HEIGHT; FABRICATION; DEPENDENCE; JUNCTIONS; LAYER;
D O I
10.1016/j.mssp.2014.03.035
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
We produced Pt(II)) complexes using the bidentate ligand N-aminopyrimidine-2-thione (APTH). The optical transmission of thin Pt-APTH films was measured. The optical bandgap of the material was 2.58 eV. With the expectation that it might have semiconductor properties and that the Pt-APTH complex might exhibit rectifier behavior when brought into appropriate contact with a semiconductor, we fabricated Pt-APTH/p-Si contacts by direct addition of a solution of Pt-APTH to the front side of p-Si wafers. Forward bias current-voltage measurements revealed satisfactory rectifying behavior for the Pt-APTH/p-Si contacts, with a mean rectification ratio of 4.40 x 10(2) and a mean barrier height of 0.765 eV. Cheung and Norde functions were used to obtain and verify some electrical characteristics of the contacts. The results obtained from both methods are compared and discussed. (C) 2014 Elsevier Ltd. All rights reserved.
引用
收藏
页码:31 / 36
页数:6
相关论文
共 41 条
[1]   REACTIONS OF OXALYL COMPOUNDS .28. A CONVENIENT SYNTHESIS OF FUNCTIONALIZED 1H-PYRIMIDINE-2-THIONES [J].
AKCAMUR, Y ;
ALTURAL, B ;
SARIPINAR, E ;
KOLLENZ, G ;
KAPPE, O ;
PETERS, K ;
PETERS, EM ;
VONSCHNERING, HG .
JOURNAL OF HETEROCYCLIC CHEMISTRY, 1988, 25 (05) :1419-1422
[2]   Effect of the binuclear Cu(II) complex interface layer on the calculation of electronic properties of Au/Cu(II) complex/n-Si organic-inorganic hybrid heterojunction [J].
Akkilic, K. ;
Ocak, Y. S. ;
Ilhan, S. ;
Kilicoglu, T. .
SYNTHETIC METALS, 2008, 158 (21-24) :969-972
[3]   The calculation of electronic properties of an Ag/chitosan/n-Si Schottky barrier diode [J].
Akkilic, Kemal ;
Uzun, Ilhan ;
Kilicoglu, Tahsin .
SYNTHETIC METALS, 2007, 157 (6-7) :297-302
[4]   Electrical and photovoltaic properties of a n-Si/chitosan/Ag photodiode [J].
Akkilic, Kernal ;
Yakuphanoglu, Fahrettin .
MICROELECTRONIC ENGINEERING, 2008, 85 (08) :1826-1830
[5]   The electrical characteristics of sn/methyl-red/p-type Si/Al contacts [J].
Aydin, M. E. ;
Turut, A. .
MICROELECTRONIC ENGINEERING, 2007, 84 (12) :2875-2882
[6]   Some electrical properties of polyaniline/p-Si/Al structure at 300 K and 77 K temperatures [J].
Aydogan, S. ;
Saglam, M. ;
Tueruet, A. .
MICROELECTRONIC ENGINEERING, 2008, 85 (02) :278-283
[7]   A study of the rectifying behaviour of aniline green-based Schottky diode [J].
Aydogan, S. ;
Gullu, O. .
MICROELECTRONIC ENGINEERING, 2010, 87 (02) :187-191
[8]   The Schottky barrier height of the rectifying Cu/pyronline-B/p-Si, Au/pyronine-B/p-Si, Sn/pyronine-B/p-Si and Al/pyronine-B/p-Si contacts [J].
Çakar, M ;
Temirci, C ;
Türüt, A .
SYNTHETIC METALS, 2004, 142 (1-3) :177-180
[9]   Rectifying pyronine-B/p-type silicon junctions formed by sublimation of pyronine-B [J].
Çakar, M ;
Türüt, A ;
Onganer, Y .
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, 2004, 15 (01) :47-53
[10]   The nonpolymeric organic compound (pyronine-B)/p-type silicon/Sn contact barrier devices [J].
Çakar, M ;
Onganer, Y ;
Türüt, A .
SYNTHETIC METALS, 2002, 126 (2-3) :213-218