Synthesis, vibrational spectra, and structure of 4'-(4aEuro3-benzo-15-crown-5)oxy-2,2':6',2aEuro3-terpyridine (L) and its transition metal complexes. Extraction and ion-selective properties of L

被引：0

作者：

Logacheva, N. M. ^{[1
]}

Baulin, V. E. ^{[2
]}

Pyatova, E. N. ^{[3
]}

Ivanova, I. S. ^{[3
]}

Tsivadze, A. Yu. ^{[1
]}

机构：

[1] Russian Acad Sci, AN Frumkin Electrochem Inst, Moscow 117071, Russia

[2] Russian Acad Sci, Inst Physiologically Act Subst, Chernogolovka 142432, Moscow Oblast, Russia

[3] Russian Acad Sci, NS Kurnakov Gen & Inorgan Chem Inst, Moscow 117907, Russia

来源：

RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2009年 / 35卷 / 09期

基金：

俄罗斯基础研究基金会;

关键词：

CROWN-ETHERS; TERPYRIDINE; CONDUCTANCE; ELECTRODES;

D O I：

10.1134/S1070328409090048

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Complexes of Co(II), Ni(II), Zn(II), and Cu(II) perchlorates and hexafluorophosphates with 4'-(4aEuro(3)-benzo-15-crown-5)oxy-2,2':6',2aEuro(3)-terpyridine (L) [M(L)(2)](ClO4)(2) center dot 3H(2)O and [M(L)(2)](PF6)(2) center dot 2H(2)O were synthesized. The spectral criteria of ligand coordination through the terpyridine nitrogen atoms were established. An assumption concerning the benzo-15-crown-5 conformation in the ligand molecule in the synthesized complexes was made. The extraction and ion-selective properties of L were studied.

引用

页码：648 / 656

页数：9

共 4 条

[1] Synthesis, vibrational spectra, and structure of 4′-(4″-benzo-15-crown-5)oxy-2,2′:6′,2″-terpyridine (L) and its transition metal complexes. Extraction and ion-selective properties of L
N. M. Logacheva
V. E. Baulin
E. N. Pyatova
I. S. Ivanova
A. Yu. Tsivadze
Russian Journal of Coordination Chemistry, 2009, 35 : 648 - 656
[2] Synthesis of 4′-(4‴-benzo-15-crown-5)-methyloxy-2,2′:6′,2″-terpyridine (L) and the crystal structure of its complexes with cobalt(II) and zinc(II): [ML2](ClO4)2 · 3H2O
A. Yu. Tsivadze
V. E. Baulin
M. S. Grigor’ev
N. M. Logacheva
A. V. Shnipov
Russian Journal of Inorganic Chemistry, 2008, 53 : 1712 - 1717
[3] Nickel(II), Cobalt(II), Copper(II), and Zinc(II) Complexes with 4′-(4′′′-Benzo-15-Crown-5)methyloxy-2,2′:6′,2"-Terpyridine: Syntheses and Vibrational Spectra
Logacheva, N. M.
Baulin, V. E.
Pyatova, E. N.
Ivanova, I. S.
Tsivadze, A. Yu.
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2009, 35 (03) : 161 - 169
[4] Synthesis, structure, optical and magnetic properties of [CrL(X)3], {L=4′-(2-pyridyl)-2,2′:6′,2"-terpyridine;: X = Cl-, N3-, NCS-}
Padhi, Sumanta Kumar
Saha, Dipankar
Sahu, Rojalm
Subramanian, Japyesan
Manivannan, Vadivelu
POLYHEDRON, 2008, 27 (06) : 1714 - 1720

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