Preparation of an aliphatic-substituted hypervalent iodine compound, tetracoordinate 1,2-iodoxetane 1-oxide, and its application to oxidation

被引：8

作者：

Kano, N ^{[1
]}

Ohashi, M ^{[1
]}

Hoshiba, K ^{[1
]}

Kawashima, T ^{[1
]}

机构：

[1] Univ Tokyo, Grad Sch Sci, Dept Chem, Bunkyo Ku, Tokyo 1130033, Japan

来源：

TETRAHEDRON LETTERS | 2004年 / 45卷 / 44期

关键词：

iodine; iodinane; 1,2-iodoxetane; oxidation;

D O I：

10.1016/j.tetlet.2004.09.022

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A tetracoordinate 1,2-iodoxetane was prepared by the fluorination of a tricoordinate 1,2-iodoxetane with xenon difluoride followed by hydrolysis. The tetracoordinate 1,2-iodoxetane oxidized alcohols and a sulfide to the corresponding aldehydes and ketones, and a sulfoxide, respectively, in good to moderate yields under mild conditions. (C) 2004 Elsevier Ltd. All rights reserved.

引用

页码：8173 / 8175

页数：3

共 22 条

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