Growth of belt-like SnS crystals from ethylenediamine solution

被引：69
作者：
An, CH
Tang, KB [1 ]
Shen, GZ
Wang, CR
Yang, Q
Hai, B
Qian, YT
机构：
[1] Univ Sci & Technol China, Dept Chem, Hefei 230026, Anhui, Peoples R China
[2] Univ Sci & Technol China, Struct Res Lab, Hefei 230026, Anhui, Peoples R China
来源：
JOURNAL OF CRYSTAL GROWTH | 2002年 / 244卷 / 3-4期
基金：
中国国家自然科学基金;
关键词：
crystal morphology; growth from solutions; semiconducting materials;
D O I：
10.1016/S0022-0248(02)01613-5
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
Tin (II) sulfide crystal belts, with tens of micrometers in width, several millimeters in length and several micrometers in thickness, was successfully grown in ethylenediamine (en) via a solvothermal route at low temperature. The products were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), induced-coupled plasma (ICP), X-ray photoelectron spectra (XPS). The vibrational property of the as-prepared SnS belt was examined by Raman spectra. The possible growth mechanism of SnS crystal belts was discussed, which revealed that the solvent (en) was crucial in the formation of belt-like SnS crystals. (C) 2002 Elsevier Science B.V. All rights reserved.
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收藏
页码：333 / 338
页数：6
相关论文
共 28 条
  • [1] THE PREPARATION AND THE ELECTRICAL AND OPTICAL PROPERTIES OF SNS CRYSTALS
    ALBERS, W
    HAAS, C
    VANDERMAESEN, F
    [J]. JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 1960, 15 (3-4) : 306 - 310
  • [2] DIMETHYLFORMAMIDE AND DIMETHYLSULFOXIDE ADDUCTS OF TIN(II) PERCHLORATES
    BASSOTELI, AR
    ANGELO, ACD
    TFOUNI, E
    STRADIOTTO, NR
    [J]. POLYHEDRON, 1984, 3 (05) : 627 - 630
  • [3] Benzyl-substituted tin chalcogenides. Efficient single-source precursors for tin sulfide, tin selenide, and Sn(SxSe1-x) solid solutions
    Boudjouk, P
    Seidler, DJ
    Grier, D
    McCarthy, GJ
    [J]. CHEMISTRY OF MATERIALS, 1996, 8 (06) : 1189 - 1196
  • [4] IR AND RAMAN-SPECTRA OF 4-6 COMPOUNDS SNS AND SNSE
    CHANDRASEKHAR, HR
    HUMPHREYS, RG
    ZWICK, U
    CARDONA, M
    [J]. PHYSICAL REVIEW B, 1977, 15 (04): : 2177 - 2183
  • [5] Thermal decomposition of sulfur-containing organotin molecular precursors to produce phase-pure SnS
    Costa, GAA
    Silva, MC
    Silva, ACB
    de Lima, GM
    Lago, RM
    Sansiviero, MTC
    [J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2000, 2 (24) : 5708 - 5711
  • [6] PHOTOCONDUCTIVITY IN TIN SULFIDE SINGLE-CRYSTALS
    ELKORASHY, AM
    [J]. PHYSICA B, 1991, 168 (04): : 257 - 267
  • [7] LOW-TEMPERATURE CHEMICAL PRECIPITATION AND VAPOR-DEPOSITION OF SNXS THIN-FILMS
    ENGELKEN, RD
    MCCLOUD, HE
    LEE, C
    SLAYTON, M
    GHOREISHI, H
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1987, 134 (11) : 2696 - 2707
  • [8] Convenient, room-temperature liquid ammonia routes to metal chalcogenides
    Henshaw, G
    Parkin, IP
    Shaw, GA
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1997, (02): : 231 - 236
  • [9] Hulliger F., 1976, Structural Chemistry of Layer-Type Phases
  • [10] Series: Physics and Chemistry of Materials with Layered Structures
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