Photocatalytic Oxidation of Cyclohexene with Molecular Oxygen Using Immobilized Vitamin B12 within Nanoreactors of Al-MCM-41

被引：0

作者：

Farzaneh, F. ^{[1
]}

Nouroozi, F. ^{[1
]}

Ghandi, M. ^{[2
]}

机构：

[1] Univ Alzahra, Dept Chem, Tehran, Iran

[2] Univ Tehran, Sch Chem, Univ Coll Sci, Tehran, Iran

来源：

POLISH JOURNAL OF CHEMISTRY | 2009年 / 83卷 / 01期

关键词：

photooxidation; vitamin B-12; Al-MCM-41; PHOTOOXIDATION; COMPLEXES;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Immobilized vitamin B-12 within nanoreactors of Al-MCM-41 (Vit.B-12/Al-MCM-41) was used as catalyst in the photooxidation of cyclohexene with molecular oxygen in CH3CN using medium pressure mercury lamp at room temperature. It was found that 99% of cyclohexene was converted to 2-cyclohexene-1-one (70%), 2-cyclohexene-1-ol (15%) and cyclohexene oxide (15%). Details of reaction are discussed.

引用

页码：123 / 130

页数：8