Photocatalytic Oxidation of Cyclohexene with Molecular Oxygen Using Immobilized Vitamin B12 within Nanoreactors of Al-MCM-41

被引：0
|
作者：
Farzaneh, F. [1 ]
Nouroozi, F. [1 ]
Ghandi, M. [2 ]
机构：
[1] Univ Alzahra, Dept Chem, Tehran, Iran
[2] Univ Tehran, Sch Chem, Univ Coll Sci, Tehran, Iran
来源：
POLISH JOURNAL OF CHEMISTRY | 2009年 / 83卷 / 01期
关键词：
photooxidation; vitamin B-12; Al-MCM-41; PHOTOOXIDATION; COMPLEXES;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Immobilized vitamin B-12 within nanoreactors of Al-MCM-41 (Vit.B-12/Al-MCM-41) was used as catalyst in the photooxidation of cyclohexene with molecular oxygen in CH3CN using medium pressure mercury lamp at room temperature. It was found that 99% of cyclohexene was converted to 2-cyclohexene-1-one (70%), 2-cyclohexene-1-ol (15%) and cyclohexene oxide (15%). Details of reaction are discussed.
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收藏
页码：123 / 130
页数：8
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