Carbon-Polymer Composite Bipolar Plate for HT-PEMFC

被引:13
作者
Ghosh, A. [1 ,2 ]
Verma, A. [1 ,2 ]
机构
[1] Indian Inst Technol Guwahati, Dept Chem Engn, Gauhati 781039, Assam, India
[2] Indian Inst Technol Guwahati, Ctr Energy, Gauhati 781039, Assam, India
关键词
Bipolar Plate; Carbon-Polymer Nanocomposite; Electrical Conductivity; Flexural Strength; Graphene; HT-PEMFC; MEMBRANE FUEL-CELLS; HIGH-TEMPERATURE; ELECTRICAL-CONDUCTIVITY; GRAPHENE; FIBER;
D O I
10.1002/fuce.201300186
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Graphene reinforced carbon-polymer composite bipolar plate is developed using resole phenol formaldehyde resin, and conductive reinforcements (natural graphite, carbon black, and carbon fiber) using compression molding technique. Graphene is reinforced into the composite to alter various properties of the composite bipolar plate. The developed composite bipolar plate is characterized and the effect of temperature on mechanical and electrical properties is investigated with an overall aim to achieve benchmark given by US-DOE and Plug Power Inc. The flexural strength and electrical conductivity of the composites was almost stable with the increase in temperature upto 175 degrees C. The composite bipolar plate maintained high in-plane and through-plane electrical conductivities, which is about 409.23 and 98Scm(-1), respectively, at 175 degrees C. The flexural strength and shore hardness of the developed composite was around 56.42MPa and 60, respectively, at 175 degrees C, and on further increase in the temperature the mechanical strengths deceases sharply. The electrical and mechanical properties of the composite bipolar plates are within the US-DoE target. However, the various properties of the composite bipolar plate could not be sustained above 175 degrees C.
引用
收藏
页码:259 / 265
页数:7
相关论文
共 42 条
[1]   Carbon materials in composite bipolar plates for polymer electrolyte membrane fuel cells: A review of the main challenges to improve electrical performance [J].
Antunes, Renato A. ;
de Oliveira, Mara C. L. ;
Ett, Gerhard ;
Ett, Volkmar .
JOURNAL OF POWER SOURCES, 2011, 196 (06) :2945-2961
[2]   Advanced anodes for high-temperature fuel cells [J].
Atkinson, A ;
Barnett, S ;
Gorte, RJ ;
Irvine, JTS ;
Mcevoy, AJ ;
Mogensen, M ;
Singhal, SC ;
Vohs, J .
NATURE MATERIALS, 2004, 3 (01) :17-27
[3]   Status and development of PEM fuel cell technology [J].
Barbir, F. ;
Yazici, S. .
INTERNATIONAL JOURNAL OF ENERGY RESEARCH, 2008, 32 (05) :369-378
[4]   Development and characterisation of electrically conductive polymeric-based blends for proton exchange membrane fuel cell bipolar plates [J].
Bouatia, S. ;
Mighri, F. ;
Bousmina, M. .
FUEL CELLS, 2008, 8 (02) :120-128
[5]   High temperature (HT) polymer electrolyte membrane fuel cells (PEMFC) - A review [J].
Chandan, Amrit ;
Hattenberger, Mariska ;
El-Kharouf, Ahmad ;
Du, Shangfeng ;
Dhir, Aman ;
Self, Valerie ;
Pollet, Bruno G. ;
Ingram, Andrew ;
Bujalski, Waldemar .
JOURNAL OF POWER SOURCES, 2013, 231 :264-278
[6]   Mechanical and physical properties of epoxy composites reinforced by vapor grown carbon nanofibers [J].
Choi, YK ;
Sugimoto, K ;
Song, SM ;
Gotoh, Y ;
Ohkoshi, Y ;
Endo, M .
CARBON, 2005, 43 (10) :2199-2208
[7]  
Cross J., 1999, IQPC FUEL CELLS INFR
[8]   Carbon Nanomaterials for Advanced Energy Conversion and Storage [J].
Dai, Liming ;
Chang, Dong Wook ;
Baek, Jong-Beom ;
Lu, Wen .
SMALL, 2012, 8 (08) :1130-1166
[9]   The rise of graphene [J].
Geim, A. K. ;
Novoselov, K. S. .
NATURE MATERIALS, 2007, 6 (03) :183-191
[10]   Graphene: Status and Prospects [J].
Geim, A. K. .
SCIENCE, 2009, 324 (5934) :1530-1534