N/B-co-doped ordered mesoporous carbon spheres by ionothermal strategy for enhancing supercapacitor performance

被引：58
作者：
Du, Juan [1 ]
Zhang, Yue [1 ]
Lv, Haijun [1 ]
Chen, Aibing [1 ,2 ]
机构：
[1] Hebei Univ Sci & Technol, Coll Chem & Pharmaceut Engn, 70 Yuhua Rd, Shijiazhuang 050018, Hebei, Peoples R China
[2] Chinese Acad Sci, Inst Coal Chem, CAS Key Lab Carbon Mat, Beijing, Peoples R China
来源：
JOURNAL OF COLLOID AND INTERFACE SCIENCE | 2021年 / 587卷
基金：
中国国家自然科学基金;
关键词：
N/B-co-doped; Order mesoporous; Carbon spheres; Ionothermal; Supercapacitor;
D O I：
10.1016/j.jcis.2020.11.037
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Heteroatom doping in carbonaceous materials is an effective way to improve the performance of super capacitors. Herein, the N/B-co-doped ordered mesoporous carbon spheres (N/B-OMC) were developed by a facile ionothermal strategy. The ordered mesoporous phenol/formaldehyde resin (PF) spheres were employed as carbon precursor, which was treated by ionothermal process using 1-butyl 3-methylimidazole tetrafronoroborate ([Bmim]BF4) as medium. The [Bmim]BF4 can be absorbed in the pores of PF spheres, leading to N/B-co-doping for the obtained carbon framework without damage in spherical morphology and ordered mesoporous structure. As a result, the dual-heteroatom doping, high surface area and enlarged mesopore size of N/B-OMC can enhance the electrochemical performance, exhibiting its promising as novel electrode materials. (c) 2020 Elsevier Inc. All rights reserved.
引用
收藏
页码：780 / 788
页数：9
相关论文
共 47 条
[1]   A novel path towards synthesis of nitrogen-rich porous carbon nanofibers for high performance supercapacitors [J].
Amiri, Ahmad ;
Conlee, Bryan ;
Tallerine, Ian ;
Kennedy, W. Joshua ;
Naraghi, Mohammad .
CHEMICAL ENGINEERING JOURNAL, 2020, 399
[2]   Molecular understanding of charge storage and charging dynamics in supercapacitors with MOF electrodes and ionic liquid electrolytes [J].
Bi, Sheng ;
Banda, Harish ;
Chen, Ming ;
Niu, Liang ;
Chen, Mingyu ;
Wu, Taizheng ;
Wang, Jiasheng ;
Wang, Runxi ;
Feng, Jiamao ;
Chen, Tianyang ;
Dinca, Mircea ;
Kornyshev, Alexei A. ;
Feng, Guang .
NATURE MATERIALS, 2020, 19 (05) :552-+
[3]   Thin-walled, mesoporous and nitrogen-doped hollow carbon spheres using ionic liquids as precursors [J].
Chen, Aibing ;
Yu, Yifeng ;
Lv, Haijun ;
Wang, Yanyan ;
Shen, Shufeng ;
Hu, Yongqi ;
Li, Bo ;
Zhang, Yue ;
Zhang, Jian .
JOURNAL OF MATERIALS CHEMISTRY A, 2013, 1 (04) :1045-1047
[4]   Nitrogen and sulfur co-doped porous carbon fibers film for flexible symmetric all-solid-state supercapacitors [J].
Chen, Long ;
Wen, Ziyan ;
Chen, Lina ;
Wang, Weipeng ;
Ai, Qing ;
Hou, Guangmei ;
Li, Yanhui ;
Lou, Jun ;
Ci, Lijie .
CARBON, 2020, 158 :456-464
[5]   Microwave-assisted KOH activation from lignin into hierarchically porous carbon with super high specific surface area by utilizing the dual roles of inorganic salts: Microwave absorber and porogen [J].
Chen, Weimin ;
Luo, Min ;
Yang, Kai ;
Zhou, Xiaoyan .
MICROPOROUS AND MESOPOROUS MATERIALS, 2020, 300
[6]   Mass fabrication of oxygen and nitrogen co-doped 3D hierarchical porous carbon nanosheets by an explosion-assisted strategy for supercapacitor and dye adsorption application [J].
Cheng, Zhiqiang ;
Wang, Zhiwei ;
Wu, Pengchao ;
Wang, Yahuan ;
Fu, Jianwei .
APPLIED SURFACE SCIENCE, 2020, 529
[7]  
Du M., 2018, J ELECTROANAL CHEM
[8]   From crude oil production nuisance to promising energy storage material: Development of high-performance asphaltene-derived supercapacitors [J].
Enayat, Shayan ;
Tran, Mai K. ;
Salpekar, Devashish ;
Kabbani, Mohamad A. ;
Babu, Ganguli ;
Ajayan, Pulickel M. ;
Vargas, Francisco M. .
FUEL, 2020, 263
[9]   Dual-Pore Mesoporous Carbon@ Silica Composite Core- Shell Nanospheres for Multidrug Delivery** [J].
Fang, Yin ;
Zheng, Gengfeng ;
Yang, Jianping ;
Tang, Haosha ;
Zhang, Yafeng ;
Kong, Biao ;
Lv, Yingying ;
Xu, Congjian ;
Asiri, Abdullah M. ;
Zi, Jian ;
Zhang, Fan ;
Zhao, Dongyuan .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2014, 53 (21) :5366-5370
[10]   Ionic liquid C16mimBF4 assisted synthesis of poly(benzoxazine-co-resol)-based hierarchically porous carbons with superior performance in supercapacitors [J].
Guo, De-Cai ;
Mi, Juan ;
Hao, Guang-Ping ;
Dong, Wei ;
Xiong, Guang ;
Li, Wen-Cui ;
Lu, An-Hui .
ENERGY & ENVIRONMENTAL SCIENCE, 2013, 6 (02) :652-659
12345