Luminescence properties of Eu3+-doped Al2( WO4)3

被引:0
作者
Macalik, L [1 ]
Hanuza, J
Hermanowicz, K
Godlewska, P
Sidorov, NV
机构
[1] Polish Acad Sci, Inst Low Temp & Struct Res, Wroclaw, Poland
[2] Univ Econ, Fac Engn & Econ, Dept Bioorgan Chem, Wroclaw, Poland
[3] Russian Acad Sci, Kola Sci Ctr, Inst Chem, Apatity, Murmansk Region, Russia
关键词
aluminium tungstate; luminescence; excitation; optical properties;
D O I
暂无
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Emission spectra of Al-2(WO4)(3) doped with Eu3+ were recorded at room temperature (orthorhombic phase) and at 10 K ( monoclinic phase). The luminescence excitation spectra and luminescence decay profiles were recorded for both structural modifications at RT and LN2T, and the luminescence lifetimes of Eu3+ have been estimated. Two-site behaviour of the optically active ions in both phases has been revealed in the luminescence studies. However, the emission decay profiles give one lifetime of the D-5(2) level, equal to 1.8 ms and 848.4 mus at room temperature and liquid nitrogen temperature, respectively. The results obtained have been explained in terms of an unusual location of Eu3+ ions inside the crystal tunnels, parallel to the c-axis.
引用
收藏
页码:145 / 152
页数:8
相关论文
共 25 条
[1]   White light emission of Eu3+-based hybrid xerogels [J].
Carlos, LD ;
Ferreira, RAS ;
Bermudez, VD ;
Molina, C ;
Bueno, LA ;
Ribeiro, SJL .
PHYSICAL REVIEW B, 1999, 60 (14) :10042-10053
[2]   EMISSION-SPECTRA AND LOCAL SYMMETRY OF THE EU3+ ION IN POLYMER ELECTROLYTES [J].
CARLOS, LD ;
VIDEIRA, ALL .
PHYSICAL REVIEW B, 1994, 49 (17) :11721-11728
[3]   Structural phase transitions and negative thermal expansion in Sc2(MoO4)3 [J].
Evans, JSO ;
Mary, TA .
INTERNATIONAL JOURNAL OF INORGANIC MATERIALS, 2000, 2 (01) :143-151
[4]   Negative thermal expansion in a large molybdate and tungstate family [J].
Evans, JSO ;
Mary, TA ;
Sleight, AW .
JOURNAL OF SOLID STATE CHEMISTRY, 1997, 133 (02) :580-583
[5]   Negative thermal expansion in Sc2(WO4)3 [J].
Evans, JSO ;
Mary, TA ;
Sleight, AW .
JOURNAL OF SOLID STATE CHEMISTRY, 1998, 137 (01) :148-160
[6]   Negative thermal expansion materials [J].
Evans, JSO ;
Mary, TA ;
Sleight, AW .
PHYSICA B, 1997, 241 :311-316
[7]   THE STRUCTURE AND SPECTROSCOPIC PROPERTIES OF AL2-XCRX(WO4)3 CRYSTALS IN ORTHORHOMBIC AND MONOCLINIC PHASES [J].
HANUZA, J ;
MACZKA, M ;
HERMANOWICZ, K ;
ANDRUSZKIEWICZ, M ;
PIETRASZKO, A ;
STREK, W ;
DEREN, P .
JOURNAL OF SOLID STATE CHEMISTRY, 1993, 105 (01) :49-69
[8]   Electronic state of trivalent ionic conductors with Sc2(WO4)3-type structure [J].
Imanaka, N ;
Tamura, S ;
Adachi, G ;
Kowada, Y .
SOLID STATE IONICS, 2000, 130 (3-4) :179-182
[9]   Trivalent rare earth ion conduction in the scandium tungstate type structure [J].
Imanaka, N ;
Tamura, S ;
Kobayashi, Y ;
Okazaki, Y ;
Hiraiwa, M ;
Ueda, T ;
Adachi, G .
JOURNAL OF ALLOYS AND COMPOUNDS, 2000, 303 :303-306
[10]   Ionic to electronic dominant conductivity in Al2(WO4)3 at high pressure and high temperature [J].
Liu, H ;
Secco, RA ;
Imanaka, N ;
Rutter, MD ;
Adachi, G ;
Uchida, T .
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 2003, 64 (02) :287-294