Advances in the synthesis of acyclic peroxides

被引：51
作者：
Gandhi, H. [1 ,2 ]
O'Reilly, K. [1 ,2 ]
Gupta, M. K. [1 ,2 ,4 ]
Horgan, C. [1 ]
O'Leary, E. M. [1 ,2 ,3 ]
O'Sullivan, T. P. [1 ,2 ,3 ]
机构：
[1] Univ Coll Cork, Dept Chem, Cork, Ireland
[2] Univ Coll Cork, Analyt & Biol Chem Res Facil, Cork, Ireland
[3] Univ Coll Cork, Sch Pharm, Cork, Ireland
[4] Cent Univ Haryana, Sch Chem Sci, Dept Chem, Mahendergarh 123031, Haryana, India
来源：
RSC ADVANCES | 2017年 / 7卷 / 32期
关键词：
TERT-BUTYL HYDROPEROXIDE; CATALYTIC ENANTIOSELECTIVE PEROXIDATION; CHAIN FATTY-ACIDS; HYDROGEN-PEROXIDE; GEMINAL BISHYDROPEROXIDES; GEM-DIHYDROPEROXIDES; ASYMMETRIC-SYNTHESIS; ORGANIC PEROXIDES; MOLECULAR-OXYGEN; C-H;
D O I：
10.1039/c6ra28489b
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Peroxide-containing compounds are an attractive synthetic target, given their widespread abundance in nature, with many displaying potent antimalarial and antimicrobial properties. This review summarises the many developments in the synthesis of acyclic peroxides, with a particular focus on the past 20 years, and seeks to update organic chemists about these new approaches. The synthetic methodologies have been subdivided into metal-catalysed reactions, organocatalytic reactions, direct oxidation reactions, miscellaneous reactions and enzymatic routes to acyclic peroxides.
引用
收藏
页码：19506 / 19556
页数：51
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