Direct grafting of poly(pentafluorophenyl acrylate) onto oxides: versatile substrates for reactive microcapillary printing and self-sorting modification

被引：23

作者：

Arnold, Rachelle M.

McNitt, Christopher D.

Popik, Vladimir V.

Locklin, Jason ^{[1
]}

机构：

[1] Univ Georgia, Coll Engn, Dept Chem, Athens, GA 30602 USA

来源：

CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 40期

基金：

美国国家科学基金会;

关键词：

POLYMER BRUSHES; CLICK REACTIONS; FILMS; KINETICS; LAYERS;

D O I：

10.1039/c3cc47597b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Poly(pentafluorophenyl acrylate) was covalently attached to silicon oxide through the direct coupling of the reactive ester to surface silanol groups. Subsequently, reactive microcapillary printing (R-mu CaP) and a one-pot, self-sorting postpolymerization modification reaction were used to generate patterns of spatially resolved chemical functionality.

引用

收藏

页码：5307 / 5309

页数：3

相关论文

共 29 条

[1] Self-Sorting Click Reactions That Generate Spatially Controlled Chemical Functionality on Surfaces [J].

Arnold, Rachelle M. ;

Locklin, Jason .

LANGMUIR, 2013, 29 (19) :5920-5926

[2] Comparative Aminolysis Kinetics of Different Active Ester Polymer Brush Platforms in Postpolymerization Modification with Primary and Aromatic Amines [J].

Arnold, Rachelle M. ;

Sheppard, Gareth R. ;

Locklin, Jason .

MACROMOLECULES, 2012, 45 (13) :5444-5450

[3] Polymer Brushes via Surface-Initiated Controlled Radical Polymerization: Synthesis, Characterization, Properties, and Applications [J].

Barbey, Raphael ;

Lavanant, Laurent ;

Paripovic, Dusko ;

Schuewer, Nicolas ;

Sugnaux, Caroline ;

Tugulu, Stefano ;

Klok, Harm-Anton .

CHEMICAL REVIEWS, 2009, 109 (11) :5437-5527

[4] A NEAR-EDGE X-RAY-ABSORPTION FINE STRUCTURE SPECTROSCOPY AND X-RAY PHOTOELECTRON-SPECTROSCOPY STUDY OF THE FILM PROPERTIES OF SELF-ASSEMBLED MONOLAYERS OF ORGANOSILANES ON OXIDIZED SI(100) [J].

BIERBAUM, K ;

KINZLER, M ;

WOLL, C ;

GRUNZE, M ;

HAHNER, G ;

HEID, S ;

EFFENBERGER, F .

LANGMUIR, 1995, 11 (02) :512-518

[5] Design and implementation of new, silicon-based, cross-coupling reactions: Importance of silicon-oxygen bonds [J].

Denmark, SE ;

Sweis, RF .

ACCOUNTS OF CHEMICAL RESEARCH, 2002, 35 (10) :835-846

[6] Dual side-reactions limit the utility of a key polymer therapeutic precursor [J].

Devenish, SRA ;

Hill, JB ;

Blunt, JW ;

Morris, JC ;

Munro, MHG .

TETRAHEDRON LETTERS, 2006, 47 (17) :2875-2878

[7] Reactive patterning via post-functionalization of polymer brushes utilizing disuccinimidyl carbonate activation to couple primary amines [J].

Diamanti, Steve ;

Arifuzzaman, Shafi ;

Elsen, Andrea ;

Genzer, Jan ;

Vaia, Richard A. .

POLYMER, 2008, 49 (17) :3770-3779

[8] Synthesis of pentafluorophenyl(meth)acrylate polymers:: New precursor polymers for the synthesis of multifunctional materials [J].

Eberhardt, M ;

Mruk, R ;

Zentel, R ;

Théato, P .

EUROPEAN POLYMER JOURNAL, 2005, 41 (07) :1569-1575

[9] Reactive microcontact printing on block copolymer films:: Exploiting chemistry in microcontacts for sub-micrometer patterning of biomolecules [J].

Feng, Chuan Liang ;

Embrechts, Anika ;

Bredebusch, Ilona ;

Schnekenburger, Juergen ;

Domschke, Wolfram ;

Vancso, G. Julius ;

Schonherr, Holger .

ADVANCED MATERIALS, 2007, 19 (02) :286-+

[10] Fabrication of robust biomolecular patterns by reactive microcontact printing on N-hydroxysuccinimide ester-containing polymer films [J].

Feng, Chuan Liang ;

Vancso, G. Julius ;

Schoenherr, Holger .

ADVANCED FUNCTIONAL MATERIALS, 2006, 16 (10) :1306-1312