An Assay of Electrodeposited Cobalt Oxide Thin Film as a Supercapacitor Electrode

被引:7
作者
Gavande, Shivani S. [1 ]
Kulkarni, Pramod S. [2 ]
Patil, Vikas B. [1 ]
Karche, Bhanudas R. [3 ]
Gavande, Shubhangi S. [3 ,4 ]
机构
[1] PAH Solapur Univ, Sch Phys Sci, Funct Mat Res Lab, Solapur, Maharashtra, India
[2] SES Polytech Coll, Solapur, Maharashtra, India
[3] Shankarrao Mohite Mahavidyala, Dept Phys, Akluj, Maharashtra, India
[4] Sangameshwar Coll, Dept Phys, Solapur, Maharashtra, India
关键词
cobalt oxide; cyclic voltammetry; electrodeposition; potentiostatic mode; PERFORMANCE EVALUATION; COOOH;
D O I
10.1002/masy.202000169
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The present research work is a humble effort to synthesize cobalt oxide supercapacitive electrode by electrodeposition method via potentiostatic mode of thin film deposition. The cobalt hydroxide material is deposited on stainless steel substrate at room temperature and annealed at 500 degrees C to form cobalt oxide thin film electrode. The structural, morphological, and wettability investigation of the as-deposited cobalt oxide thin film electrode is done by XRD-analysis, SEM characterization, and contact angle measurement, respectively. The supercapacitive properties are investigated in aqueous 1M Na(2)SO(4)electrolyte by cyclic voltametry and galvanostatic charge-discharge analysis. The results of the investigations are maximum specific capacitance of 284.4 F g(-1)at a scan rate 5 mV s(-1), specific energy 4.325 Wh kg(-1), specific power 3 kW kg(-1), and Coulomb efficiency 53.75%. The results so obtained promote cobalt oxide to be a challenging material for energy storage devices and supercapacitor applications.
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页数:6
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共 21 条
  • [1] New approaches for synthesizing γIII-CoOOH by soft chemistry
    Bardé, F
    Palacin, MR
    Beaudoin, B
    Delahaye-Vidal, A
    Tarascon, JM
    [J]. CHEMISTRY OF MATERIALS, 2004, 16 (02) : 299 - 306
  • [2] Raman spectroscopy of cemented cobalt on zinc substrates
    Bockman, O
    Ostvold, T
    Voyiatzis, GA
    Papatheodorou, GN
    [J]. HYDROMETALLURGY, 2000, 55 (01) : 93 - 105
  • [3] Physicochemical and supercapacitive properties of electroplated nickel oxide electrode: effect of solution molarity
    Dhole, I. A.
    Navale, Y. H.
    Pawar, C. S.
    Navale, S. T.
    Patil, V. B.
    [J]. JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, 2018, 29 (07) : 5675 - 5687
  • [4] Performance evaluation of galvanostatically deposited nickel oxide electrode for electrochemical supercapacitors
    Dhole, I. A.
    Navale, S. T.
    Navale, Y. H.
    Jadhav, Y. M.
    Pawar, C. S.
    Suryavanshi, S. S.
    Patil, V. B.
    [J]. JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, 2017, 28 (15) : 10819 - 10829
  • [5] Supercapacitive Performance of Electrodeposited Cobalt Oxide Electrode
    Dhole, Indrajeet A.
    Tonape, Mallikarjun M.
    Pawar, Udayraj T.
    Gavande, Shubhangi S.
    Pawar, Shailesh G.
    Patil, V. B.
    [J]. MACROMOLECULAR SYMPOSIA, 2019, 387 (01)
  • [6] THE RAMAN-SPECTRA OF CO3O4
    HADJIEV, VG
    ILIEV, MN
    VERGILOV, IV
    [J]. JOURNAL OF PHYSICS C-SOLID STATE PHYSICS, 1988, 21 (07): : L199 - L201
  • [7] Synthesis of the CoOOH fine nanoflake film with the high rate capacitance property
    Hosono, Eiji
    Fujihara, Shinobu
    Honma, Iraru
    Ichihara, Masaki
    Zhou, Haoshen
    [J]. JOURNAL OF POWER SOURCES, 2006, 158 (01) : 779 - 783
  • [8] Performance evaluation of symmetric supercapacitor based on cobalt hydroxide [Co(OH)2] thin film electrodes
    Jagadale, A. D.
    Kumbhar, V. S.
    Dhawale, D. S.
    Lokhande, C. D.
    [J]. ELECTROCHIMICA ACTA, 2013, 98 : 32 - 38
  • [9] Influence of electrodeposition modes on the supercapacitive performance of Co3O4 electrodes
    Jagadale, Ajay D.
    Kumbhar, Vijay S.
    Bulakhe, Ravindra N.
    Lokhande, Chandrakant D.
    [J]. ENERGY, 2014, 64 : 234 - 241
  • [10] Photoelectrochemical solar cells with chemically grown CdO rice grains on flexible stainless steel substrates
    Jambure, S. B.
    Lokhande, C. D.
    [J]. MATERIALS LETTERS, 2013, 106 : 133 - 136