Graphene Oxide Catalyzed C-N/C-S/[3+2] Cyclization Cascade for Green Synthesis of Thiazolidinone in Water

被引：3

作者：

Mahata, Suhasini ^{[1
]}

Sahu, Anjumala ^{[1
]}

Shukla, Prashant ^{[2
]}

Rai, Ankita ^{[2
]}

Singh, Manorama ^{[1
]}

Rai, Vijai K. ^{[1
]}

机构：

[1] Guru Ghasidas Vishwavidyalaya, Dept Chem, Bilaspur 495009, Chhattisgarh, India

[2] Jawaharlal Nehru Univ, Sch Phys Sci, New Delhi 110029, India

来源：

LETTERS IN ORGANIC CHEMISTRY | 2018年 / 15卷 / 08期

关键词：

Graphene oxide; imine; mercaptoacetic acid; water; organic; 1,3-thiazolidin-4-one; ONE-POT SYNTHESIS; SELECTIVE-INHIBITION; 4-THIAZOLIDINONES; EFFICIENT; CARBOCATALYST; MICROWAVE; ACID; ACTIVATION; CHEMISTRY; ANALOGS;

D O I：

10.2174/1570178614666171002145250

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

In this paper, first graphene oxide catalyzed one-pot three-component green synthesis of 1,3-thiazolidin-4-one using amine, aldehyde and mercapto acetic acid in water has been reported. The reaction is affected via sequential C-N and C-S bond formation and ring transformation reactions leading to thiazolidin-4-ones formation. The use of water as solvent at room temperature, good to excellent yields of pure products (75-92%) and operational simplicity are the salient features of the envisaged protocol. The graphene oxide catalyst is very mild, effective and most of its activity is preserved after being reused for five times.

引用

页码：665 / 672

页数：8

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