A new colorimetric and far-red fluorescent probe for hydrazine with a large red-shifted absorption spectrum

被引：19

作者：

Xu, Zujun ^{[1
]}

Pang, Mengmeng ^{[2
]}

Li, Changwang ^{[1
]}

Zhu, Baocun ^{[2
]}

机构：

[1] Zhangqiu 4 Middle Sch, Jinan 250200, Shandong, Peoples R China

[2] Univ Jinan, Shandong Prov Engn Technol Res Ctr Ecol Carbon Si, Sch Resources & Environm, Jinan 250022, Peoples R China

来源：

LUMINESCENCE | 2017年 / 32卷 / 03期

关键词：

colorimetric probe; far-red fluorescence; fluorescent probe; hydrazine; ratiometric detection; LARGE EMISSION SHIFT; IN-VIVO APPLICATIONS; AQUEOUS-SOLUTION; LIVING CELLS; SELECTIVE DEPROTECTION; SUBSTITUTED HYDRAZINES; RATIOMETRIC DETECTION; RATIONAL DESIGN; RAPID DETECTION; LIVE CELLS;

D O I：

10.1002/bio.3232

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Recently, growing attention has been paid to the detection of hydrazine (NH2NH2) because of its important roles in industrial chemical and high toxicity to human beings. Herein, we have constructed a new colorimetric and far-red fluorescent probe containing a receptor of 4-bromobutanoate to selectively detect hydrazine. The probe could detect hydrazine quantitatively in the range of 40-500M with the detection limit of 2.9M. In addition, the probe could monitor hydrazine by the ratiometric method with a large (185nm) red-shifted absorption spectrum, and the color changes from yellow to blue make it as a naked-eye' indicator for hydrazine. Consequently, our proposed probe would be of great benefit for monitoring hydrazine in aqueous solution.

引用

页码：466 / 470

页数：5

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