Structural and chemical complexity in multicomponent inorganic-organic framework materials

被引：21

作者：

Feller, Russell K. ^{[1
,2
]}

Cheetham, Anthony K. ^{[1
,2
]}

机构：

[1] Univ Calif Santa Barbara, Mat Res Lab, Santa Barbara, CA 93106 USA

[2] Univ Cambridge, Dept Mat Sci & Met, Cambridge CB2 3QZ, England

来源：

CRYSTENGCOMM | 2009年 / 11卷 / 06期

关键词：

POROUS COORDINATION POLYMERS; CRYSTAL-STRUCTURE; COPPER(II); CHEMISTRY; NETWORK; LADDERS; STORAGE; LN;

D O I：

10.1039/b820718f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A family of coordination polymers with remarkable structural and chemical complexity is produced when Cu and Zn are combined with 5-hydroxyisophthalic acid and 4,4'-bipyridyl. The structures of these four- and five-component phases are fully ordered, with the two metals occupying different sites and the ligands playing distinct bridging roles in each structure. In one five-component phase, oxalate forms as a product of partial ligand decomposition and is incorporated alongside the two original ligands into the resultant solid. The valence of Cu and the Cu/Zn ratios differ between the phases, in spite of similar synthetic conditions.

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收藏

页码：980 / 985

页数：6

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