Structural and chemical complexity in multicomponent inorganic-organic framework materials

被引：21
作者：
Feller, Russell K. [1 ,2 ]
Cheetham, Anthony K. [1 ,2 ]
机构：
[1] Univ Calif Santa Barbara, Mat Res Lab, Santa Barbara, CA 93106 USA
[2] Univ Cambridge, Dept Mat Sci & Met, Cambridge CB2 3QZ, England
来源：
CRYSTENGCOMM | 2009年 / 11卷 / 06期
关键词：
POROUS COORDINATION POLYMERS; CRYSTAL-STRUCTURE; COPPER(II); CHEMISTRY; NETWORK; LADDERS; STORAGE; LN;
D O I：
10.1039/b820718f
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A family of coordination polymers with remarkable structural and chemical complexity is produced when Cu and Zn are combined with 5-hydroxyisophthalic acid and 4,4'-bipyridyl. The structures of these four- and five-component phases are fully ordered, with the two metals occupying different sites and the ligands playing distinct bridging roles in each structure. In one five-component phase, oxalate forms as a product of partial ligand decomposition and is incorporated alongside the two original ligands into the resultant solid. The valence of Cu and the Cu/Zn ratios differ between the phases, in spite of similar synthetic conditions.
引用
收藏
页码：980 / 985
页数：6
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