Molecular and crystal structure of quinoline-2-aldehyde thiosemicarbazone

被引：16

作者：

Bourosh, P. N. ^{[1
]}

Revenko, M. D. ^{[2
]}

Gdaniec, M. ^{[3
]}

Stratulat, E. F. ^{[2
]}

Simonov, Yu. A. ^{[1
]}

机构：

[1] Moldavian Acad Sci, Inst Appl Sci, Kishinev, Moldova

[2] Moldova State Univ, Kishinev, Moldova

[3] Adam Mickiewicz Univ, Fac Chem, Poznan, Poland

来源：

JOURNAL OF STRUCTURAL CHEMISTRY | 2009年 / 50卷 / 03期

关键词：

quinoline-2-aldehyde thiosemicarbazone; synthesis; structure; configuration; crystal structure; METAL-COMPLEXES; SALICYLALDEHYDE; SEMICARBAZONES; COPPER(II);

D O I：

10.1007/s10947-009-0078-z

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The molecular and crystal structure of quinoline-2-aldehyde thiosemicarbazone is determined. The thiosemicarbazide fragment has cis-arrangement of terminal nitrogen atoms relative to the central N-C bond. The structure is based on a centrosymmetric dimer formed by hydrogen bonds between NH groups and sulfur atoms of thiosemicarbazide fragments of the neighboring molecules. In the crystal, the dimers are joined with each other through a system of hydrogen bonds and intermolecular pi-pi interactions.

引用

页码：510 / 513

页数：4

共 24 条

[1] Synthesis, characterization and X-ray crystallographic structural study of copper(II) and nickel(II) complexes of the 2-quinoline carboxaldehyde Schiff base of S-methyldithiocarbazate (Hqaldsme) [J].

Ali, M. Akbar ;

Mirza, A. H. ;

Bujan, Fatriah Hj ;

Hamid, Malai Haniti S. A. ;

Bernhardt, Paul V. .

POLYHEDRON, 2006, 25 (17) :3245-3252

[2] The Cambridge Structural Database: a quarter of a million crystal structures and rising [J].

Allen, FH .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 2002, 58 (3 PART 1) :380-388

[3] SYNTHETIC, SPECTROSCOPIC, AND X-RAY CRYSTALLOGRAPHIC STUDIES ON BINUCLEAR COPPER(II) COMPLEXES WITH A TRIDENTATE NNS-BONDING 2-FORMYLPYRIDINE THIOSEMICARBAZONE LIGAND - THE CHARACTERIZATION OF BOTH NEUTRAL AND DEPROTONATED COORDINATED LIGAND STRUCTURE [J].

BINGHAM, AG ;

BOGGE, H ;

MULLER, A ;

AINSCOUGH, EW ;

BRODIE, AM .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1987, (03) :493-499

[4] MOLECULAR-STRUCTURE AND ELECTRONIC-STRUCTURE OF 2-PYRIDINE-CARBALDEHYDE THIOSEMICARBAZONE [J].

BIYUSHKIN, VN ;

CHUMAKOV, YM ;

SAMUS, NM ;

BAKA, ID .

JOURNAL OF STRUCTURAL CHEMISTRY, 1987, 28 (01) :119-121

[5]

BIYUSHKIN VN, 1982, KHIM FARM ZH+, V16, P1090

[6] Structure of quinoline-8-aldehyde S-methyl thiosemicarbazone dihydrochloride [J].

Botoshanskii, M. ;

Bourosh, P. N. ;

Revenko, M. D. ;

Korzha, I. D. ;

Simonov, Yu. A. ;

Panfilie, T. .

JOURNAL OF STRUCTURAL CHEMISTRY, 2009, 50 (01) :181-184

[7] Main group metal complexes of semicarbazones and thiosemicarbazones.: A structural review [J].

Casas, JS ;

García-Tasende, MS ;

Sordo, J .

COORDINATION CHEMISTRY REVIEWS, 2000, 209 :197-261

[8] STRUCTURE OF SALICYLALDEHYDE THIOSEMICARBAZONE [J].

CHATTOPADHYAY, D ;

MAZUMDAR, SK ;

BANERJEE, T ;

GHOSH, S ;

MAK, TCW .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1988, 44 :1025-1028

[9]

CHUMAKOV YM, 1985, J STRUCT CHEM+, V26, P929, DOI 10.1007/BF00748365

[10] Synthesis and characterization of some mono- and dinuclear molybdenum(VI) thiosemicarbazonato complexes [J].

Cindric, M ;

Vrdoljak, VN ;

Strukan, N ;

Kamenar, B .

POLYHEDRON, 2005, 24 (02) :369-376

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