Interaction between calix[4]arene derivative bearing adenino units and complementary nucleosides at the air-water interface

被引:14
|
作者
Guo, X [1 ]
Lu, GY [1 ]
Li, Y [1 ]
机构
[1] Nanjing Univ, Dept Chem, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China
基金
中国国家自然科学基金;
关键词
monolayer; calix[4]arene; Langmuir-Blodgett films; nucleoside; interaction;
D O I
10.1016/j.tsf.2004.01.108
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The monolayers of the amphiphilic calix[4]arene derivatives at the lower rim with two adenino units on the surface of pure water, the aqueous subphases containing complementary nucleosides were studied by film balance measurement and relaxation experiments. LB films deposited from all subphases were investigated by UV spectra and FT-IR spectra. All the results indicate that the interaction between the adenino units in the headgroup of amphiphilic calix[4]arene derivatives and the complementary nucleosides in the subphase takes place through multiple complementary hydrogen bonding and the nucleosides in the subphases can be transferred to solid substrates along with their monolayers. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:264 / 268
页数:5
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