Synthesis of monodispersed PEDOT/Au hollow nanospheres and its application for electrochemical determination of dopamine and uric acid

被引：29
作者：
Ali, Ahmat [1 ]
Jamal, Ruxangul [1 ,2 ]
Abdiryim, Tursun [1 ,2 ]
Huang, Xueli [3 ]
机构：
[1] Xinjiang Univ, Coll Chem & Chem Engn, Educ Minist China, Key Lab Petr & Gas Fine Chem, Urumqi 830046, Peoples R China
[2] Xinjiang Univ, Key Lab Funct Polymers, Urumqi 830046, Peoples R China
[3] Xinjiang Univ, Coll Chem & Chem Engn, Urumqi 830046, Peoples R China
来源：
JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 2017年 / 787卷
基金：
中国国家自然科学基金;
关键词：
Poly(3,4-ethylenedioxythiophene); Au; Nanosphere; Dopamine; Uric acid; GLASSY-CARBON ELECTRODE; ASCORBIC-ACID; AU NANOCOMPOSITE; GRAPHENE OXIDE; ONE-STEP; DOPED POLY(3,4-ETHYLENEDIOXYTHIOPHENE); SELECTIVE DETECTION; GOLD NANOPARTICLES; SENSOR; FILM;
D O I：
10.1016/j.jelechem.2017.01.051
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
Poly(3,4-ethylenedioxythiophene)/Gold (PEDOT/Au) hollow nanospheres with the ratio of EDOT and HAuCl4 from 2:1 to 1:2 were synthesized by in-situ polymerization method. The synergism between the PEDOT and Au explored for detection of Dopamine (DA) and Uric acid (UA) in neutral phosphate buffer solutions (PBS 7.0). It was found that the monodispersed PEDOT and PEDOT/Au hollow nanospheres had been successfully prepared. Electrochemical experiments showed that the PEDOT/Au(1:1) modified electrode revealed excellent electrocatalytic activity with faster electron charge transfer kinetics. The results from differential pulse voltammetry (DPV) experiments revealed that the PEDOT/Au(1:1) electrode has excellent linear response with 0.15 mu mu-330 mu M and 1.5 mu M-150 mu M for the determination of DA and UA, respectively. The detection limits(S/N = 3) were found to be 0.07 mu M and 0.08 mu M for determination of DA and UA, respectively. The PEDOT/Au(1:1) modified electrode also had good reproducibility, repeatability and excellent stability. (C) 2017 Elsevier B.V. All rights reserved.
引用
收藏
页码：110 / 117
页数：8
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