The inhibited polymerization of lithium methacrylate and copolymerization with acrylonitrile

被引：3
作者：
Czerniawski, T [1 ]
机构：
[1] Nicholas Copernicus Univ, Fac Chem, PL-87100 Torun, Poland
来源：
EUROPEAN POLYMER JOURNAL | 2000年 / 36卷 / 03期
关键词：
D O I：
10.1016/S0014-3057(99)00105-6
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Results for the determination of initiation rate of the polymerization reaction of lithium methacrylate and its copolymerization with acrylonitrile in dimethylformamide at various temperatures are reported. The inhibition method involving the stable radical N,N-diphenyl-N'-picrylhydrazyl has been used. The initiation rate constant 2k(df) and the activation energy of initiation E-2kdf have been determined. An influence of the initial monomer mixture concentration on the measured quantities has been revealed. (C) 2000 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：635 / 642
页数：8
相关论文
共 12 条
12