Fluorescent Styryl Dyes Based on Novel 4-Methoxy-9-Methyi-9H-Carbazole-3-Carbaldehyde-Synthesis, Photophysical Properties and DFT Computations

被引：4

作者：

Umape, Prashant G. ^{[1
]}

Gawale, Yogesh ^{[1
]}

Sekar, Nagaiyan ^{[1
]}

机构：

[1] Inst Chem Technol, Dept Dyestuff Technol, Tinctorial Chem Grp, Bombay 400019, Maharashtra, India

来源：

JOURNAL OF FLUORESCENCE | 2014年 / 24卷 / 04期

关键词：

Styryl compounds; Solid state fluorescence; Fluorescent; Solvatochromism; Solvatofluorism; TD-DFT; PUSH-PULL CHROMOPHORES; LIGHT-EMITTING DEVICES; SENSITIZED SOLAR-CELLS; PROTON-TRANSFER ESIPT; STATE DIPOLE-MOMENTS; EXCITED-STATE; CARBAZOLE DERIVATIVES; ELECTROLUMINESCENT MATERIALS; ORGANIC-DYES; COMPLEXES;

D O I：

10.1007/s10895-014-1389-9

中图分类号：

Q5 [生物化学];

学科分类号：

071010 ; 081704 ;

摘要：

Novel carbazole based styryl derivatives (6a-6c) having styryl group at third position and a methoxy substitution were synthesized by condensing 4-methoxy-9-methyl-9H-carbazole-3-carbaldehyde 3 and different active methylene derivatives (5a-5c). Evaluated photophysical properties of these synthesized novel chromophores, studied the effect of solvent polarity on absorption, emission and quantum yield of these styryl derivatives. DFT and TD-DFT computations are carried out to study structural, molecular, electronic and photophysical parameters of dyes. The ratio of ground state to excited state dipole moment was calculated using Bakhshiev and Kawski-Chamma-Viallet correlations.

引用

页码：1087 / 1098

页数：12

共 22 条

[21] Excited-State Properties of Metal-Free ((Z)-2-Cyano-3-(4-((E)-2-(6-(4-methoxyphenyl)-9-octyl-9H-carbazol-3-yl)vinyl)phenyl)acrylic Acid and (E)-2-Cyano-3-(4-((E)-4-(diphenylamino)styryl)phenyl)acrylic Acid) and Ru-Based (N719 and Z907) Dyes and Photoinduced Charge Transfer Processes in FTO/TiCl4/TiO2/Dye Photoanodes Fabricated by Conventional Staining and Potential-Assisted Adsorption
Niedzwiedzki, Dariusz M.
Kandregula, Ganapathi Rao
Sivanadanam, Jagadeeswari
Ramanujam, Kothandaraman
JOURNAL OF PHYSICAL CHEMISTRY A, 2020, 124 (22) : 4333 - 4344
[22] Synthesis, structure, and photoluminescence properties of a novel 3D 3d-4f heterometallic polymer: Pr4(H2O)9Cu3.5Cl0.5(Bpdc)6.5(OH)2 • 5H2O (H2Bpdc=2,2′-bipyridyl-5,5-dicarboxylic acid)
Cheng, H. L.
Shi, D. Y.
Zhao, J. W.
Geng, Z. D.
Chen, L. J.
Ma, P. T.
Niu, J. Y.
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2011, 37 (04) : 302 - 308

← 1 2 3 →