Energetics of reactions in a dielectric barrier discharge with argon carrier gas: VII anhydrides

被引:3
|
作者
Mertens, Jeremy [1 ]
Watson, Sean [2 ,3 ]
Nisol, Bernard [2 ,3 ]
Wertheimer, Michael R. [2 ,3 ]
Reniers, Francois [1 ]
机构
[1] Univ Libre Bruxelles, Fac Sci Chim Analyt & Chim Interfaces, 2 Blvd Triomphe, B-1050 Brussels, Belgium
[2] Polytech Montreal, GCM, Box 6079, Montreal, PQ H3C 3A7, Canada
[3] Polytech Montreal, Dept Engn Phys, Box 6079, Montreal, PQ H3C 3A7, Canada
基金
加拿大自然科学与工程研究理事会;
关键词
anhydride; atmospheric pressure; dielectric barrier discharge; energy exchange; polymerization mechanism; PLASMA POLYMERIZATION; DOUBLE-BONDS; HYDROLYSIS;
D O I
10.1002/ppap.201800186
中图分类号
O59 [应用物理学];
学科分类号
摘要
The method developed for fundamental understanding of energetic exchanges between monomer molecules and argon carrier gas in a dielectric barrier discharge (DBD) has previously proven merit. In this seventh article related to this methodology, research has been extended to a new family of precursors: anhydrides. Monomers (typically parts per thousand) were mixed with 10slm of Ar in a 20kHz, 8kV (peak-to-peak) DBD corresponding to an energy per cycle of 1600J for pure Ar. For each of the investigated monomers E-m, the energy absorbed per molecule was plotted as a function of precursor flow rate. The influence of chemical structure (C/O ratio, unsaturation) has been investigated and compared with previous data for other types of precursors. Thin plasma polymer coatings were deposited; in addition to measuring deposition rates, we also present relationships between E-m values, spectro-ellipsometric and FTIR measurements.
引用
收藏
页数:7
相关论文
共 50 条
  • [31] Decomposition of dimethylamine gas with dielectric barrier discharge
    Ye, Zhaolian
    Zhao, Jie
    Huang, Hong Ying
    Ma, Fei
    Zhang, Renxi
    JOURNAL OF HAZARDOUS MATERIALS, 2013, 260 : 32 - 39
  • [32] Flue Gas Desulfurization by Dielectric Barrier Discharge
    Bai, Mindi
    Leng, Baiyu
    Mao, Shoulei
    Li, Chaoqun
    PLASMA CHEMISTRY AND PLASMA PROCESSING, 2016, 36 (02) : 511 - 521
  • [33] The dielectric barrier discharge as a detector for gas chromatography
    Kunze, K
    Miclea, M
    Franzke, J
    Niemax, K
    SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY, 2003, 58 (08) : 1435 - 1443
  • [34] Flue Gas Desulfurization by Dielectric Barrier Discharge
    Mindi Bai
    Baiyu Leng
    Shoulei Mao
    Chaoqun Li
    Plasma Chemistry and Plasma Processing, 2016, 36 : 511 - 521
  • [35] Optical emission kinetics of argon inductively coupled plasma and argon dielectric barrier discharge
    Zhang, JL
    Yu, SJ
    Ma, TC
    VACUUM, 2002, 65 (3-4) : 327 - 333
  • [36] Generation of Homogeneous Atmospheric-Pressure Dielectric Barrier Discharge in a Large-Gap Argon Gas
    Fang, Zhi
    Shao, Tao
    Ji, Shengchang
    Pan, Jun
    Zhang, Cheng
    IEEE TRANSACTIONS ON PLASMA SCIENCE, 2012, 40 (07) : 1884 - 1890
  • [37] Determination of ultratrace nitrogen in pure argon gas by dielectric barrier discharge-molecular emission spectrometry
    Li, Wei
    Jiang, Xiaoming
    Xu, Kailai
    Hou, Xiandeng
    Zheng, Chengbin
    MICROCHEMICAL JOURNAL, 2011, 99 (01) : 114 - 117
  • [38] Surface discharge induced interactions of filaments in argon dielectric barrier discharge at atmospheric pressure
    Li, Xuechen
    Zhang, Panpan
    Chu, Jingdi
    Zhang, Qi
    Lin, Xiaotong
    Jia, Pengying
    Dong, Lifang
    PHYSICS OF PLASMAS, 2017, 24 (10)
  • [40] Study on Spectral Characteristics of Pulsed Argon Vacuum Dielectric Barrier Discharge
    Wang Wei
    Wang Yong-gang
    Wu Zhong-hang
    Rao Jun-feng
    Jiang Song
    Li Zi
    SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43 (02) : 455 - 459