Synergistic flame retardant effect of graphite powder in EVA/LDH composites

被引:17
|
作者
Jia, C. X. [1 ]
Chen, X. L. [1 ]
Qian, Y. [1 ]
机构
[1] Qingdao Univ Sci & Technol, Coll Environm & Safety Engn, Qingdao 266042, Peoples R China
基金
中国国家自然科学基金;
关键词
Flame retardant; Synthesis; Layered double hydroxide; Red mud; Graphite powder; LAYERED DOUBLE HYDROXIDE; VINYL ACETATE COPOLYMER; PHOSPHORUS; NANOCOMPOSITES;
D O I
10.1179/1743289813Y.0000000072
中图分类号
TB33 [复合材料];
学科分类号
摘要
Red mud (RM) is a large quantity waste product in the production of alumina. There is still no efficient way to deal with it in the world. Using RM as a raw material to synthesise Mg-Al-Fe ternary layered double hydroxide (LDH) is a feasible way to solve this global problem. The synthesised LDH was characterised by X-ray diffraction. The flame retardant and thermal degradation properties of ethylene-vinyl acetate/layered double hydroxide/graphite powder (EVA/LDH/GP) composites have been studied using cone calorimeter test (CCT), scanning electron microscopy (SEM), and thermogravimetry-Fourier transform infrared spectrometry (TG-IR). The CCT data indicate that heat release rates of EVA/LDH/GP composites decrease greatly in comparison with those of EVA, EVA/RM and EVA/LDH composites. The morphological structures of charred residues observed by SEM give positive evidence that the compact char residue layers formed from EVA/LDH/GP composites. The TG-IR is used to characterise volatilised products formed in the thermal degradation process.
引用
收藏
页码:46 / 53
页数:8
相关论文
共 50 条
  • [1] Synergistic flame retardant effects of Fe-OMMT with LDH in EVA/LDH composites
    Chen, X. L.
    Jiao, C. M.
    Li, S. X.
    Zhang, J.
    PLASTICS RUBBER AND COMPOSITES, 2013, 42 (08) : 323 - 326
  • [2] Synergistic flame retardant effect of metal hydroxide and nanoclay in EVA composites
    Yen, Ynh-Yue
    Wang, Hsin-Ta
    Guo, Wen-Jen
    POLYMER DEGRADATION AND STABILITY, 2012, 97 (06) : 863 - 869
  • [3] Synergistic Flame-retardant Effects of Aluminum Oxide with Layered Double Hydroxides in EVA/LDH Composites
    Jiao, Chuanmei
    Chen, Xilei
    Zhang, Jun
    JOURNAL OF THERMOPLASTIC COMPOSITE MATERIALS, 2010, 23 (04) : 501 - 512
  • [4] Combustion Characteristics and Synergistic Effects of Red Phosphorus Masterbatch With Expandable Graphite in the Flame Retardant HDPE/EVA Composites
    Tang, Mengqi
    Chen, Man
    Xu, Yang
    Chen, Xiaolang
    Sun, Zhidan
    Zhang, Zhibin
    POLYMER ENGINEERING AND SCIENCE, 2015, 55 (12): : 2884 - 2892
  • [5] Synergistic effect between hollow glass beads and aluminium hydroxide in flame retardant EVA composites
    Liu, L.
    Liu, J. L.
    Chen, X. L.
    Jiao, C. M.
    PLASTICS RUBBER AND COMPOSITES, 2014, 43 (03) : 77 - 81
  • [6] The synergistic effect of functionalized montmorillonite with intumescent flame retardant in EVA
    Yan Liu
    Iranian Polymer Journal, 2015, 24 : 197 - 202
  • [7] The synergistic effect of functionalized montmorillonite with intumescent flame retardant in EVA
    Liu, Yan
    IRANIAN POLYMER JOURNAL, 2015, 24 (03) : 197 - 202
  • [8] Comparative study on synergistic effect of LDH and zirconium phosphate with aluminum trihydroxide on flame retardancy of EVA composites
    Kalali, Ehsan Naderi
    De Juan, Sergio
    Wang, Xin
    Nie, Shibin
    Wang, Rui
    Wang, De-Yi
    JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2015, 121 (02) : 619 - 626
  • [9] Comparative study on synergistic effect of LDH and zirconium phosphate with aluminum trihydroxide on flame retardancy of EVA composites
    Ehsan Naderi Kalali
    Sergio De Juan
    Xin Wang
    Shibin Nie
    Rui Wang
    De-Yi Wang
    Journal of Thermal Analysis and Calorimetry, 2015, 121 : 619 - 626
  • [10] Comparative study of the synergistic effect of binary and ternary LDH with intumescent flame retardant on the properties of polypropylene composites
    Wang, Xin
    Spoerer, Yvonne
    Leuteritz, Andreas
    Kuehnert, Ines
    Wagenknecht, Udo
    Heinrich, Gert
    Wang, De-Yi
    RSC ADVANCES, 2015, 5 (96): : 78979 - 78985