Synthesis and structure of novel dinitrosyl iron complexes [Fe2(μ-SCH2CH2NHR)2(NO)4]

被引：4
作者：
Davidovich, P. B. [1 ]
Gurzhy, V. V. [2 ]
Belyaev, A. N. [1 ]
机构：
[1] St Petersburg State Inst Technol Tech Univ, St Petersburg 190013, Russia
[2] St Petersburg State Univ, St Petersburg 190013, Russia
来源：
RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2014年 / 84卷 / 04期
关键词：
coordination compounds of iron; nitrogen monoxide donors; structure; DFT calculations; NITRIC-OXIDE; LIGAND;
D O I：
10.1134/S1070363214040203
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Two novel dinitrosyl iron complexes with thiolate bridging ligands [Fe-2(mu-SCH2CH2NHR)(2)(NO)(4)] (R = Ac, Boc), derived from the cysteamine complex [Fe-2(mu-SCH2CH2NH3)(2)(NO)(4)](2+) are described. The complex with acylated cysteamine is characterized by X-ray diffraction analysis. The cysteamine complex is a convenient precursor for modification of the bridging ligand.
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收藏
页码：719 / 721
页数：3
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