Synthesis and structure of novel dinitrosyl iron complexes [Fe2(μ-SCH2CH2NHR)2(NO)4]

被引：4

作者：

Davidovich, P. B. ^{[1
]}

Gurzhy, V. V. ^{[2
]}

Belyaev, A. N. ^{[1
]}

机构：

[1] St Petersburg State Inst Technol Tech Univ, St Petersburg 190013, Russia

[2] St Petersburg State Univ, St Petersburg 190013, Russia

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2014年 / 84卷 / 04期

关键词：

coordination compounds of iron; nitrogen monoxide donors; structure; DFT calculations; NITRIC-OXIDE; LIGAND;

D O I：

10.1134/S1070363214040203

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two novel dinitrosyl iron complexes with thiolate bridging ligands [Fe-2(mu-SCH2CH2NHR)(2)(NO)(4)] (R = Ac, Boc), derived from the cysteamine complex [Fe-2(mu-SCH2CH2NH3)(2)(NO)(4)](2+) are described. The complex with acylated cysteamine is characterized by X-ray diffraction analysis. The cysteamine complex is a convenient precursor for modification of the bridging ligand.

引用

页码：719 / 721

页数：3

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