Catalytic oxidation of gaseous benzene with ozone over zeolite-supported metal oxide nanoparticles at room temperature

被引：76

作者：

Huang, Haibao ^{[1
,2
]}

Huang, Wenjun ^{[1
]}

Xu, Ying ^{[1
]}

Ye, Xinguo ^{[1
]}

Wu, Muyan ^{[1
]}

Shao, Qiming ^{[1
]}

Ou, Guochao ^{[1
]}

Peng, Zheran ^{[1
]}

Shi, Jingxuan ^{[1
]}

Chen, Jiandong ^{[1
]}

Feng, Qiuyu ^{[1
]}

Zan, Yujie ^{[1
]}

Huang, Huiling ^{[1
]}

Hu, Peng ^{[1
]}

机构：

[1] Sun Yat Sen Univ, Sch Environm Sci & Engn, Guangzhou 510275, Guangdong, Peoples R China

[2] Guangdong Prov Key Lab Environm Pollut Control &, Guangzhou 510275, Guangdong, Peoples R China

来源：

CATALYSIS TODAY | 2015年 / 258卷

关键词：

Metal oxides; MnO2/ZSM-5; Catalytic ozonation; Benzene; CO2; selectivity; MANGANESE OXIDES; GAS-PHASE; PHOTOCATALYTIC OXIDATION; MNOX/GAMMA-ALUMINA; WATER-VAPOR; TOLUENE; AIR; DECOMPOSITION; MNOX; REGENERATION;

D O I：

10.1016/j.cattod.2015.01.006

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

To improve the capacity for complete oxidation of gaseous benzene by catalytic ozonation, a series of metal oxides catalysts (Mn, Co, Ni, Cu, Zn and Ce) were prepared by impregnation method using ZSM-5 zeolite as the support. The developed metal oxides were highly dispersed in nanosize on the support. Among them, MnO2/ZSM-5 showed the best activity toward catalytic ozonation of benzene. Benzene can be completely removed even at room temperature and CO2 selectivity reached 84.7%. MnO2/ZSM-5 was quite effective due to the production of highly reactive oxidizing species from ozone decomposition. The activities toward benzene catalytic ozonation are closely related to the capacity for ozone decomposition. (C) 2015 Elsevier B.V. All rights reserved.

引用

页码：627 / 633

页数：7

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