A novel solid acid for synthesis of bisphenol A

被引:15
作者
Hou, Lijie [1 ]
Cai, Qinghai [1 ]
Lu, Bin [1 ]
Li, Xuemei [1 ]
Xiao, Xue [1 ]
Han, Yuanyuan [1 ]
Cui, Shuhan [1 ]
机构
[1] Harbin Normal Univ, Dept Chem, Harbin 150080, Peoples R China
关键词
bisphenol A; solid acid; synthesis; catalyst;
D O I
10.1007/s10562-006-0155-2
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A novel solid acid was prepared from boric, phosphorous and sulfuric acid by a simple method, and characterized by FT-IR, XRD and TG. Surprisingly, the prepared solid acid is an effective catalyst for the synthesis of bisphenol A from condensation of phenol with acetone. The high conversion of acetone (91.8%) and selectivity of bisphenol A (93.4%) were achieved in the presence of the novel catalyst.
引用
收藏
页码:153 / 157
页数:5
相关论文
共 19 条
[1]  
Baykal A, 2001, TURK J CHEM, V25, P425
[2]   ADDITIVITY RULES FOR ESTIMATION OF THERMOCHEMICAL PROPERTIES [J].
BENSON, SW ;
CRUICKSHANK, FR ;
GOLDEN, DM ;
HAUGEN, GR ;
ONEAL, HE ;
RODGERS, AS ;
SHAW, R ;
WALSH, R .
CHEMICAL REVIEWS, 1969, 69 (03) :279-+
[3]   Selective synthesis of Bisphenol-A over mesoporous MCM silica catalysts functionalized with sulfonic acid groups [J].
Das, D ;
Lee, JF ;
Cheng, SF .
JOURNAL OF CATALYSIS, 2004, 223 (01) :152-160
[4]  
DONALD AE, 1997, Patent No. 9734688
[5]   Relations between morphology and catalytic activity of ion exchanger catalysts for synthesis of bisphenol A [J].
Jerábek, K ;
Hanková, L ;
Prokop, Z ;
Lundquist, EG .
APPLIED CATALYSIS A-GENERAL, 2002, 232 (1-2) :181-188
[6]   Synthesis of bisphenol A catalyzed by Et3NHCl-AlCl3 ionic liquids [J].
Jia, LJ ;
Hua, CY ;
Dai, LY ;
Shan, YK .
REACTION KINETICS AND CATALYSIS LETTERS, 2004, 81 (02) :235-240
[7]  
JIN T, 1986, J PHYS CHEM-US, V90, P4194
[8]   The simulated moving-bed reactor for production of bisphenol A [J].
Kawase, M ;
Inoue, Y ;
Araki, T ;
Hashimoto, K .
CATALYSIS TODAY, 1999, 48 (1-4) :199-209
[9]  
Li ZP, 2004, J INORG MATER, V19, P249
[10]  
MICHELE P, 1979, Patent No. 7903483