Recent progress in electrochemical reduction of CO2 by oxide-derived copper catalysts

被引：56

作者：

Wang, S. ^{[1
]}

Kou, T. ^{[1
]}

Baker, S. E. ^{[2
]}

Duoss, E. B. ^{[2
]}

Li, Y. ^{[1
]}

机构：

[1] Univ Calif Santa Cruz, Dept Chem & Biochem, Santa Cruz, CA 95064 USA

[2] Lawrence Livermore Natl Lab, Livermore, CA 94550 USA

来源：

MATERIALS TODAY NANO | 2020年 / 12卷

关键词：

Copper oxides; Electrocatalysis; Carbon dioxide; CARBON-DIOXIDE; ELECTROCATALYTIC REDUCTION; MECHANISTIC INSIGHTS; SUBSURFACE OXYGEN; SELECTIVITY; ELECTRODES; ETHYLENE; ELECTROREDUCTION; SURFACE; NANOPARTICLES;

D O I：

10.1016/j.mtnano.2020.100096

中图分类号：

TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

Oxide-derived copper (Cu) catalysts often show significantly improved performance for carbon dioxide (CO2) reduction reactions compared with metallic Cu. In this article, we summarize the recently reported methods for preparing oxide-derived Cu catalysts and discuss the current understanding of the reaction mechanisms, including the role of mixed oxidation states of copper, subsurface oxygen, local pH, and electrolyte. Finally, we share our thoughts about the current challenges for oxide-derived Cu catalysts and the potential solutions. (C) 2020 Elsevier Ltd. All rights reserved.

引用

页数：13

共 63 条

[1] CO2 Activation over Catalytic Surfaces [J].

Alvarez, Andrea ;

Borges, Marta ;

Jose Corral-Perez, Juan ;

Giner Olcina, Joan ;

Hu, Lingjun ;

Cornu, Damien ;

Huang, Rui ;

Stoian, Dragos ;

Urakawa, Atsushi .

CHEMPHYSCHEM, 2017, 18 (22) :3135-3141

[2] Nature and Distribution of Stable Subsurface Oxygen in Copper Electrodes During Electrochemical CO2 Reduction [J].

Cavalca, Filippo ;

Ferragut, Rafael ;

Aghion, Stefano ;

Eilert, Andre ;

Diaz-Morales, Oscar ;

Liu, Chang ;

Koh, Ai Leen ;

Hansen, Thomas W. ;

Pettersson, Lars G. M. ;

Nilsson, Anders .

JOURNAL OF PHYSICAL CHEMISTRY C, 2017, 121 (45) :25003-25009

[3] Electrochemical Reduction of Carbon Dioxide to Ethane Using Nanostructured Cu2O-Derived Copper Catalyst and Palladium(II) Chloride [J].

Chen, Chung Shou ;

Wan, Jane Hui ;

Yeo, Boon Siang .

JOURNAL OF PHYSICAL CHEMISTRY C, 2015, 119 (48) :26875-26882

[4] Reaction Mechanisms for the Electrochemical Reduction of CO2 to CO and Formate on the Cu(100) Surface at 298 K from Quantum Mechanics Free Energy Calculations with Explicit Water [J].

Cheng, Tao ;

Xiao, Hai ;

Goddard, William A., III .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2016, 138 (42) :13802-13805

[5] HIGH-RATE GAS-PHASE CO2 REDUCTION TO ETHYLENE AND METHANE USING GAS-DIFFUSION ELECTRODES [J].

COOK, RL ;

MACDUFF, RC ;

SAMMELLS, AF .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1990, 137 (02) :607-608

[6] Catalyst electro-redeposition controls morphology and oxidation state for selective carbon dioxide reduction [J].

De Luna, Phil ;

Quintero-Bermudez, Rafael ;

Cao-Thang Dinh ;

Ross, Michael B. ;

Bushuyev, Oleksandr S. ;

Todorovic, Petar ;

Regier, Tom ;

Kelley, Shana O. ;

Yang, Peidong ;

Sargent, Edward H. .

NATURE CATALYSIS, 2018, 1 (02) :103-110

[7] CO2 electroreduction to ethylene via hydroxide-mediated copper catalysis at an abrupt interface [J].

Dinh, Cao-Thang ;

Burdyny, Thomas ;

Kibria, Md Golam ;

Seifitokaldani, Ali ;

Gabardo, Christine M. ;

de Arquer, F. Pelayo Garcia ;

Kiani, Amirreza ;

Edwards, Jonathan P. ;

De Luna, Phil ;

Bushuyev, Oleksandr S. ;

Zou, Chengqin ;

Quintero-Bermudez, Rafael ;

Pang, Yuanjie ;

Sinton, David ;

Sargent, Edward H. .

SCIENCE, 2018, 360 (6390) :783-787

[8] Morphology Matters: Tuning the Product Distribution of CO2 Electroreduction on Oxide-Derived Cu Foam Catalysts [J].

Dutta, Abhijit ;

Rahaman, Motiar ;

Luedi, Nicola C. ;

Broekmann, Peter .

ACS CATALYSIS, 2016, 6 (06) :3804-3814

[9] Subsurface Oxygen in Oxide-Derived Copper Electrocatalysts for Carbon Dioxide Reduction [J].

Eilert, Andre ;

Cavalca, Filippo ;

Roberts, F. Sloan ;

Osterwalder, Juerg ;

Liu, Chang ;

Favaro, Marco ;

Crumlin, Ethan J. ;

Ogasawara, Hirohito ;

Friebel, Daniel ;

Pettersson, Lars G. M. ;

Nilsson, Anders .

JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2017, 8 (01) :285-290

[10] Subsurface oxide plays a critical role in CO2 activation by Cu(111) surfaces to form chemisorbed CO2, the first step in reduction of CO2 [J].

Favaro, Marco ;

Xiao, Hai ;

Cheng, Tao ;

Goddard, William A., III ;

Yano, Junko ;

Crumlin, Ethan J. .

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2017, 114 (26) :6706-6711

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