A novel TGS-like inorganic-organic hybrid and a preliminary investigation of its possible ferroelectric behavior

被引:41
作者
Li, YH [1 ]
Qu, ZR [1 ]
Zhao, H [1 ]
Ye, Q [1 ]
Xing, LX [1 ]
Wang, XS [1 ]
Xiong, RG [1 ]
You, XZ [1 ]
机构
[1] Nanjing Univ, Inst Coordinat Chem, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China
关键词
D O I
10.1021/ic034672c
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The homochiral inorganic-organic hybrid compound (H(3)NHPA)-(SnCl3)(2)(H2O)(3) [1, (S)-4-(4'-aminophenyl)-2-aminobutanoic acid diammonium trichloride stannite triaqua] has a TGS (triglycine sulfate)-like structure. Preliminary investigation suggests a possible ferroelectric behavior with a saturation spontaneous polarization (P-s) of ca. 3.5 muC(.)cm(-2), which is slightly greater than that of TGS (P-s = 3.0 muC(.)cm(-2)).
引用
收藏
页码:3768 / 3770
页数:3
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