A novel TGS-like inorganic-organic hybrid and a preliminary investigation of its possible ferroelectric behavior

被引:42
作者
Li, YH [1 ]
Qu, ZR [1 ]
Zhao, H [1 ]
Ye, Q [1 ]
Xing, LX [1 ]
Wang, XS [1 ]
Xiong, RG [1 ]
You, XZ [1 ]
机构
[1] Nanjing Univ, Inst Coordinat Chem, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China
关键词
D O I
10.1021/ic034672c
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The homochiral inorganic-organic hybrid compound (H(3)NHPA)-(SnCl3)(2)(H2O)(3) [1, (S)-4-(4'-aminophenyl)-2-aminobutanoic acid diammonium trichloride stannite triaqua] has a TGS (triglycine sulfate)-like structure. Preliminary investigation suggests a possible ferroelectric behavior with a saturation spontaneous polarization (P-s) of ca. 3.5 muC(.)cm(-2), which is slightly greater than that of TGS (P-s = 3.0 muC(.)cm(-2)).
引用
收藏
页码:3768 / 3770
页数:3
相关论文
共 48 条
  • [1] Agullo-Lopez F., 1994, Electrooptics phenomena, materials and applications
  • [2] Intermolecular interactions in nonorganic crystal engineering
    Braga, D
    Grepioni, F
    [J]. ACCOUNTS OF CHEMICAL RESEARCH, 2000, 33 (09) : 601 - 608
  • [3] Two-dimensional ferroelectric films
    Bune, AV
    Fridkin, VM
    Ducharme, S
    Blinov, LM
    Palto, SP
    Sorokin, AV
    Yudin, SG
    Zlatkin, A
    [J]. NATURE, 1998, 391 (6670) : 874 - 877
  • [4] Dantlgraber G, 2002, ANGEW CHEM INT EDIT, V41, P2408, DOI 10.1002/1521-3773(20020703)41:13<2408::AID-ANIE2408>3.0.CO
  • [5] 2-M
  • [6] Chemistry beyond the molecule
    Desiraju, GR
    [J]. NATURE, 2001, 412 (6845) : 397 - 400
  • [7] DESIRAJU GR, 1989, DESIGN ORGANIC SOLID
  • [8] Crystal engineering of NLO materials based on metal-organic coordination networks
    Evans, OR
    Lin, WB
    [J]. ACCOUNTS OF CHEMICAL RESEARCH, 2002, 35 (07) : 511 - 522
  • [9] Evans OR, 1999, ANGEW CHEM INT EDIT, V38, P536, DOI 10.1002/(SICI)1521-3773(19990215)38:4<536::AID-ANIE536>3.0.CO
  • [10] 2-3