Semicontinuous Emulsion Co-polymerization of Vinyl Acetate and VeoVa10

被引：19

作者：

Agirre, Amaia ^{[1
,2
]}

Calvo, Inigo ^{[1
,2
,3
]}

Weitzel, Hans-Peter ^{[4
]}

Hergeth, Wolf-Dieter ^{[4
]}

Asua, Jose M. ^{[1
,2
]}

机构：

[1] Univ Basque Country UPV EHU, Fac Ciencias Quim, POLYMAT, Donostia San Sebastian 20018, Spain

[2] Univ Basque Country UPV EHU, Fac Ciencias Quim, Dept Quim Aplicada, Donostia San Sebastian 20018, Spain

[3] Oribay Mirror Buttons SL R&D Dept, Donostia San Sebastian 20018, Spain

[4] Wacker Chem AG, D-84489 Burghausen, Germany

来源：

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH | 2014年 / 53卷 / 22期

关键词：

POPULATION BALANCE-EQUATIONS; FREE-RADICAL POLYMERIZATION; MOLECULAR-WEIGHT DISTRIBUTION; SECONDARY PARTICLE FORMATION; CONTINUOUS LOOP REACTOR; POLY(VINYL ALCOHOL); MINIEMULSION POLYMERIZATION; LENGTH DISTRIBUTION; MATHEMATICAL-MODEL; PIVOT TECHNIQUE;

D O I：

10.1021/ie4032499

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

The high solids semicontinuous emulsion polymerization of VAc and VeoVa10 using poly(vinyl alcohol) (PVOH) as polymeric stabilizer is investigated. It is shown that (i) PVOH strongly affects the kinetics of the process and (ii) the formation of PVOH-graft-poly(VAc-co-VeoVa10) leads to an overestimation of the gel content and an underestimation of the sol molecular weight when the standard characterization techniques are directly applied. A new method to properly characterize the MWD of these copolymers is presented. A mathematical model is used to analyze the effects of surfactant and initiator on the kinetics and polymer microstructure.

引用

页码：9282 / 9295

页数：14

共 77 条

[41]

Gonzalez GSM, 1996, J POLYM SCI POL CHEM, V34, P849, DOI 10.1002/(SICI)1099-0518(19960415)34:5<849::AID-POLA14>3.0.CO

[42]

2-I

[43] (Mini)emulsion polymerization:: Effect of the segregation degree on polymer architecture [J].

Gonzalez, Iker ;

Paulis, Maria ;

de la Cal, Jose C. ;

Asua, Jose M. .

MACROMOLECULAR REACTION ENGINEERING, 2007, 1 (06) :635-642

[44] CHOICE OF MONOMER PARTITION MODEL IN MATHEMATICAL-MODELING OF EMULSION COPOLYMERIZATION SYSTEMS [J].

GUGLIOTTA, LM ;

ARZAMENDI, G ;

ASUA, JM .

JOURNAL OF APPLIED POLYMER SCIENCE, 1995, 55 (07) :1017-1039

[45]

Hutchinson RA, 1995, DECH MONOG, V131, P467

[46] Molecular weight distribution modeling of radical polymerization in a CSTR with long chain branching through transfer to polymer and terminal double bond (TDB) propagation [J].

Iedema, PD ;

Grcev, S ;

Hoefsloot, HCJ .

MACROMOLECULES, 2003, 36 (02) :458-476

[47] Knowledge-based choice of the initiator type for monomer removal by postpolymerization [J].

Ilundain, P ;

Alvarez, D ;

Da Cunha, L ;

Salazar, R ;

Barandiaran, MJ ;

Asua, JM .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2002, 40 (23) :4245-4249

[48] Postpolymerization of vinyl acetate-containing latexes [J].

Ilundain, P ;

Da Cunha, L ;

Salazar, R ;

Alvarez, D ;

Barandiaran, MJ ;

Asua, JM .

JOURNAL OF APPLIED POLYMER SCIENCE, 2002, 83 (04) :923-928

[49] CONTINUOUS EMULSION POLYMERIZATION - MODELING OSCILLATIONS IN VINYL-ACETATE POLYMERIZATION [J].

KIPARISSIDES, C ;

MACGREGOR, JF ;

HAMIELEC, AE .

JOURNAL OF APPLIED POLYMER SCIENCE, 1979, 23 (02) :401-418

[50] On the solution of population balance equations by discretization - III. Nucleation, growth and aggregation of particles [J].

Kumar, S ;

Ramkrishna, D .

CHEMICAL ENGINEERING SCIENCE, 1997, 52 (24) :4659-4679

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