The rheological properties of gelatin gels containing κ-carrageenan. The role of polysaccharide

被引:19
作者
Derkach, S. R. [1 ]
Voron'ko, N. G. [1 ]
Maklakova, A. A. [1 ]
Kondratyuk, Yu. V. [1 ]
机构
[1] Murmansk State Tech Univ, Murmansk 183010, Russia
关键词
BEHAVIOR; PROTEIN;
D O I
10.1134/S1061933X14020021
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The influence of an anionic polysaccharide, kappa-carrageenan, on the rheological properties of low-concentration (1.0 wt %) gelatin gels has been studied in a wide range of low polysaccharide concentrations (1 x 10(-3)-5 x 10(-1) wt %) at a temperature of 14.0A degrees C and pH values slightly higher than the isoelectric point of gelatin. The parameters characterizing the rheological properties of the gels are governed by the mass ratio between the polysaccharide and gelatin, which are able to form (bio)polyelectrolyte complexes in aqueous systems. There is a critical kappa-carrageenan-to-gelatin mass ratio Z a parts per thousand... 0.1, above which the yield stress of the gels and their effective viscosit at stresses exceeding the yield point drastically rise. The increase in these rheological parameters correlates with a growth in the particle size of kappa-carrageenan-gelatin polyelectrolyte complexes, which are formed in the aqueous bulk phase at an elevated temperature and precede gelation.
引用
收藏
页码:146 / 152
页数:7
相关论文
共 36 条
[1]   Phase separation in aqueous gelatin-κ-carrageenan systems [J].
Antonov, YA ;
Gonçalves, MP .
FOOD HYDROCOLLOIDS, 1999, 13 (06) :517-524
[2]  
Brandrup I., 1999, POLYM HDB
[3]  
Derkatch S. R., 2001, International Journal of Applied Mechanics and Engineering, V6, P659
[4]   Conformational ordering and gelation of gelatin in mixtures with soluble polysaccharides [J].
Harrington, Jennifer C. ;
Morris, Edwin R. .
FOOD HYDROCOLLOIDS, 2009, 23 (02) :327-336
[5]  
Haug IJ, 2009, WOODHEAD PUBL FOOD S, P142, DOI 10.1533/9781845695873.142
[6]   Physical behaviour of fish gelatin-κ-carrageenan mixtures [J].
Haug, IJ ;
Draget, KI ;
Smidsrod, A .
CARBOHYDRATE POLYMERS, 2004, 56 (01) :11-19
[7]   Mixed gels made from protein and kappa-carrageenan [J].
Ipsen, R .
CARBOHYDRATE POLYMERS, 1995, 28 (04) :337-339
[8]  
Izmailova VN, 2004, POLYM SCI SER C+, V46, P73
[9]  
IZMAILOVA VN, 1974, STRUKTUROOBRAZOVANIE
[10]  
Izumrudov VA, 2008, USP KHIM+, V77, P401