共 11 条
[11]
Wrobel J., 1992, ALKALOIDS CHEM PHARM, V42, P249
Glypetelotine, a sulphur-containing indole alkaloid from Glycosmis petelotii
被引：16
作者：
Cuong, NM
Taylor, WC
Sung, TV
机构：
[1] Vietnam Natl Ctr Nat Sci & Technol, Inst Chem, Hanoi, Vietnam
[2] Univ Sydney, Sch Chem, Dept Organ Chem, Sydney, NSW 2006, Australia
关键词：
Glycosmis petelotii;
Rutaceae;
glypetelotine;
indole;
sulphur-containing alkaloid;
thiocarbamate;
D O I：
10.1016/S0031-9422(99)00402-1
中图分类号：
Q5 [生物化学];
Q7 [分子生物学];
学科分类号：
071010 ;
081704 ;
摘要：
A sulphur-containing indole alkaloid, glypetelotine, has been isolated fi om the leaves of the endemic Vietnamese plant Glycosmis petelotii Guill. (Rutaceae). The structure of glypetelotine was determined to be S-methyl N,N-2-[(1H)-indol-3-ethyl]methyl thiocarbamate from the spectroscopic evidence including UV, IR, MS,H-1- and C-13-NMR, NOESY, HETCOR and DQF-H-1-H-1 COSY. Conformational isomerism of the compound, resulting from the tertiary amide-like unit, was studied by dynamic H-1-NMR spectroscopy carried out in different solvents and at different temperatures. (C) 1999 Elsevier Science Ltd. All rights reserved.
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页码：1711 / 1714
页数：4
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