CRYSTALLOGRAPHIC ANALYSIS OF A SAMARIUM(III) COMPLEX WITH 1,3,5-TRIS(1-IMIDAZOLYL)BENZENE

被引：0
|
作者：
Wu, S. [1 ,2 ]
Wang, S. [1 ,2 ]
Zhu, M. [1 ,2 ]
Gao, E. [1 ,2 ,3 ]
机构：
[1] Shenyang Univ Chem Technol, Key Lab Liaoning Inorgan Mol Based Chem, Shenyang, Peoples R China
[2] Shenyang Univ Chem Technol, Dept Coordinat Chem, Shenyang, Peoples R China
[3] Univ Sci & Technol Liaoning, Sch Chemical Engn, Anshan, Peoples R China
来源：
JOURNAL OF STRUCTURAL CHEMISTRY | 2020年 / 61卷 / 12期
关键词：
complex; samarium(III); crystal structure; METAL-ORGANIC FRAMEWORKS; LUMINESCENT; SYSTEMS; MOF;
D O I：
10.1134/S0022476620120124
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
In this paper, a new samarium(III) complex with 1,3,5-tris(1-imidazolyl)benzene(tib) was synthesized via the solvent thermal reaction. The single crystal of the complex is measured by X-ray diffraction and subjected to crystallographic and conformational analyses. The crystal is monoclinic: a = 8.5589(12) angstrom, b = 12.2883(14) angstrom, c = 21.109(3) angstrom, alpha = 90 degrees, beta = 98.585(4)degrees, gamma = 90 degrees, V = 2195.3(5) angstrom(3), space group P2(1)/n, Z = 4, rho(c) = 2.044 mg/m(3), R = 0.0513. The asymmetric unit contains one samarium(III) center, eight O atoms from nitrate ions in solvent, and two N atoms from two different tib ligands.
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页码：1945 / 1951
页数：7
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