Asymmetric behaviour of Li/Li symmetric cells for Li metal batteries

被引：45
作者：
Koo, Dongho [1 ]
Kwon, Bomee [1 ]
Lee, Jeonghyeop [1 ]
Lee, Kyu Tae [1 ]
机构：
[1] Seoul Natl Univ, Sch Chem & Biol Engn, Inst Chem Proc, 1 Gwanak Ro, Seoul, South Korea
来源：
CHEMICAL COMMUNICATIONS | 2019年 / 55卷 / 65期
基金：
新加坡国家研究基金会;
关键词：
LITHIUM-METAL; LAYER; DEPOSITION; MECHANISMS; LIQUID; ANODE;
D O I：
10.1039/c9cc04082j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The failure mechanism of Li metal electrodes has not been fully understood yet. Herein, the asymmetric behavior of Li metal electrodes in Li/Li symmetric cells is demonstrated in terms of electrochemical performance and changes in the morphology of Li metal. This finding sheds light on developing Li metal electrodes.
引用
收藏
页码：9637 / 9640
页数：4
相关论文
共 32 条
  • [1] Electrochemical in situ investigations of SEI and dendrite formation on the lithium metal anode
    Bieker, Georg
    Winter, Martin
    Bieker, Peter
    [J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2015, 17 (14) : 8670 - 8679
  • [2] Dendritic growth mechanisms in lithium/polymer cells
    Brissot, C
    Rosso, M
    Chazalviel, JN
    Lascaud, S
    [J]. JOURNAL OF POWER SOURCES, 1999, 81 : 925 - 929
  • [3] Prospects for Dendrite-Free Cycling of Li Metal Batteries
    Chen, Qing
    Geng, Ke
    Sieradzki, K.
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2015, 162 (10) : A2004 - A2007
  • [4] High-Voltage Lithium-Metal Batteries Enabled by Localized High-Concentration Electrolytes
    Chen, Shuru
    Zheng, Jianming
    Mei, Donghai
    Han, Kee Sung
    Engelhard, Mark H.
    Zhao, Wengao
    Xu, Wu
    Liu, Jun
    Zhang, Ji-Guang
    [J]. ADVANCED MATERIALS, 2018, 30 (21)
  • [5] Promise and reality of post-lithium-ion batteries with high energy densities
    Choi, Jang Wook
    Aurbach, Doron
    [J]. NATURE REVIEWS MATERIALS, 2016, 1 (04):
  • [6] Challenges Facing Lithium Batteries and Electrical Double-Layer Capacitors
    Choi, Nam-Soon
    Chen, Zonghai
    Freunberger, Stefan A.
    Ji, Xiulei
    Sun, Yang-Kook
    Amine, Khalil
    Yushin, Gleb
    Nazar, Linda F.
    Cho, Jaephil
    Bruce, Peter G.
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 51 (40) : 9994 - 10024
  • [7] CRYSTAL-CHEMISTRY OF ELECTROCHEMICALLY INSERTED LIXV2O5
    COCCIANTELLI, JM
    DOUMERC, JP
    POUCHARD, M
    BROUSSELY, M
    LABAT, J
    [J]. JOURNAL OF POWER SOURCES, 1991, 34 (02) : 103 - 111
  • [8] Dendrite-Free Lithium Deposition via Self-Healing Electrostatic Shield Mechanism
    Ding, Fei
    Xu, Wu
    Graff, Gordon L.
    Zhang, Jian
    Sushko, Maria L.
    Chen, Xilin
    Shao, Yuyan
    Engelhard, Mark H.
    Nie, Zimin
    Xiao, Jie
    Liu, Xingjiang
    Sushko, Peter V.
    Liu, Jun
    Zhang, Ji-Guang
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (11) : 4450 - 4456
  • [9] Enabling Stable Lithium Metal Anode via 3D Inorganic Skeleton with Superlithiophilic Interphase
    Fan, Lei
    Li, Siyuan
    Liu, Lei
    Zhang, Weidong
    Gao, Lina
    Fu, Yao
    Chen, Fang
    Li, Jing
    Zhuang, Houlong L.
    Lu, Yingying
    [J]. ADVANCED ENERGY MATERIALS, 2018, 8 (33)
  • [10] Lithium metal stripping/plating mechanisms studies: A metallurgical approach
    Gireaud, L.
    Grugeon, S.
    Laruelle, S.
    Yrieix, B.
    Tarascon, J. -M.
    [J]. ELECTROCHEMISTRY COMMUNICATIONS, 2006, 8 (10) : 1639 - 1649
1234