Synthesis of poly[(cyanophenyl)silylene-p-phenylene]s as patternable ceramics precursors

被引：5

作者：

Ohshita, Joji ^{[1
]}

Iida, Toshiyuki ^{[1
]}

Izumi, Yuki ^{[1
]}

Kunai, Atsutaka ^{[1
]}

机构：

[1] Hiroshima Univ, Grad Sch Engn, Dept Appl Chem, Higashihiroshima 7398527, Japan

来源：

JOURNAL OF THE CERAMIC SOCIETY OF JAPAN | 2006年 / 114卷 / 1330期

关键词：

Organosilicon polymer; poly (silylenephenylene); heat-resistance; conducting pattern; ceramic precursor;

D O I：

10.2109/jcersj.114.529

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

hPoly (silylene-p-phenylene) s bearing cyanophenyl groups were prepared and their application to patternable precursors of conducting ceramic films was studied. When polymer films were irradiated in air through a photomask, then heated at high temperature, only the non-irradiated area was converted to conducting ceramic films with the conductivities of 1.1-2.2 x 10(2) S/cm, while the irradiated area became an insulator.

引用

收藏

页码：529 / 532

页数：4

相关论文

共 23 条

[1] Synthesis and efficient energy transfer in a three-chromophore energy gradient of regioregular silylene-spaced divinylarene copolymers [J].

Cheng, YJ ;

Luh, TY .

MACROMOLECULES, 2005, 38 (11) :4563-4568

[2] MECHANISM OF PYROLYSIS OF POLYCARBOSILANES - POLY(SILYLETHYLENE) AND POLY(DIMETHYLSILYLETHYLENE) [J].

CORRIU, RJP ;

LECLERCQ, D ;

MUTIN, PH ;

PLANEIX, JM ;

VIOUX, A .

ORGANOMETALLICS, 1993, 12 (02) :454-462

[3] Photoactivated hydrosilation curing of a ceramic precursor: Crosslinking and pyrolysis of branched oligo[(methylsilylene)methylene] [J].

Fry, BE ;

Guo, A ;

Neckers, DC .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1997, 538 (1-2) :151-161

[4] Synthesis and lithographic patterning of polycarbosilanes with pendant cobalt carbonyl clusters [J].

Greenberg, S ;

Clendenning, SB ;

Liu, K ;

Manners, I ;

Aouba, S ;

Ruda, HE .

MACROMOLECULES, 2005, 38 (06) :2023-2026

[5] New highly heat-resistant polymers containing silicon: Poly(silyleneethynylenephenyleneethynylene)s [J].

Itoh, M ;

Inoue, K ;

Iwata, K ;

Mitsuzuka, M ;

Kakigano, T .

MACROMOLECULES, 1997, 30 (04) :694-701

[6] A NOVEL SYNTHESIS AND EXTREMELY HIGH THERMAL-STABILITY OF POLY[(PHENYLSILYLENE)-ETHYNYLENE-1,3-PHENYLENEETHYNYLENE] [J].

ITOH, M ;

MITSUZUKA, M ;

IWATA, K ;

INOUE, K .

MACROMOLECULES, 1994, 27 (26) :7917-7919

[7]

Kim DS, 1999, J POLYM SCI POL CHEM, V37, P2933, DOI 10.1002/(SICI)1099-0518(19990801)37:15<2933::AID-POLA26>3.3.CO

[8]

2-B

[9] Poly(silyleneethynylenephenylene) and poly(silylenephenyleneethynylenephenylene)s: Synthesis and photophysical properties related to charge transfer [J].

Kwak, G ;

Masuda, T .

MACROMOLECULES, 2002, 35 (10) :4138-4142

[10]

Ohshita J, 1998, ACTA POLYM, V49, P379, DOI 10.1002/(SICI)1521-4044(199808)49:8<379::AID-APOL379>3.0.CO