A review on the status and challenges of electrocatalysts in lithium-sulfur batteries

被引：322

作者：

He, Jiarui ^{[1
,2
]}

Manthiram, Arumugam ^{[1
]}

机构：

[1] Univ Texas Austin, Mat Sci & Engn Program, Austin, TX 78712 USA

[2] Univ Texas Austin, Texas Mat Inst, Austin, TX 78712 USA

来源：

ENERGY STORAGE MATERIALS | 2019年 / 20卷

关键词：

Lithium-sulfur batteries; Catalytic effect; Host materials; Lithium polysulfides; Shuttle effect; EFFICIENT POLYSULFIDE MEDIATOR; METAL-ORGANIC FRAMEWORK; HIGH-PERFORMANCE; HIGHLY EFFICIENT; FREESTANDING CATHODE; CAPACITY CATHODE; RATIONAL DESIGN; POROUS CARBON; GRAPHENE FOAM; REDOX;

D O I：

10.1016/j.ensm.2019.04.038

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Lithium-sulfur (Li-S) batteries, which have a high theoretical specific capacity (1,675 mA h g(-1) of S) and a high energy density (2,600 Wh kg(-1) of S), have received a great deal of attention in recent years. Intense research efforts have been made to solve the outstanding issues in Li-S batteries. Various catalysts with high activity for stabilizing the lithium-polysulfide shuttle process and thus improving the electrochemical performance of Li-S batteries are reviewed here. Challenges and prospects for designing highly efficient catalysts for Li-S batteries are discussed.

引用

页码：55 / 70

页数：16

共 119 条

[1] Electrocatalytic Polysulfide Traps for Controlling Redox Shuttle Process of Li-S Batteries [J].

Al Salem, Hesham ;

Babu, Ganguli ;

Rao, Chitturi V. ;

Arava, Leela Mohana Reddy .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2015, 137 (36) :11542-11545

[2] Transition Metal Dichalcogenide Atomic Layers for Lithium Polysulfides Electrocatalysis [J].

Babu, Ganguli ;

Masurkar, Nirul ;

Al Salem, Hesham ;

Arave, Leela Mohana Reddy .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2017, 139 (01) :171-178

[3] Electrocatalysis of Lithium Polysulfides: Current Collectors as Electrodes in Li/S Battery Configuration [J].

Babu, Ganguli ;

Ababtain, Khalid ;

Ng, K. Y. Simon ;

Arava, Leela Mohana Reddy .

SCIENTIFIC REPORTS, 2015, 5

[4] Refined Sulfur Nanoparticles Immobilized in Metal-Organic Polyhedron as Stable Cathodes for Li-S Battery [J].

Bai, Linyi ;

Chao, Dongliang ;

Xing, Pengyao ;

Tou, Li Juan ;

Chen, Zhen ;

Jana, Avijit ;

Shen, Ze Xiang ;

Zhao, Yanli .

ACS APPLIED MATERIALS & INTERFACES, 2016, 8 (23) :14328-14333

[5] Functional Mesoporous Carbon-Coated Separator for Long-Life, High-Energy Lithium-Sulfur Batteries [J].

Balach, Juan ;

Jaumann, Tony ;

Klose, Markus ;

Oswald, Steffen ;

Eckert, Juergen ;

Giebeler, Lars .

ADVANCED FUNCTIONAL MATERIALS, 2015, 25 (33) :5285-5291

[6] Polyphenylene Tetrasulfide as an Inherently Flexible Cathode Material for Rechargeable Lithium Batteries [J].

Bhargav, Amruth ;

Bell, Michaela Elaine ;

Cui, Yi ;

Fu, Yongzhu .

ACS APPLIED ENERGY MATERIALS, 2018, 1 (11) :5859-5864

[7] Conductive Lewis Base Matrix to Recover the Missing Link of Li2S8 during the Sulfur Redox Cycle in Li-S Battery [J].

Chen, Jia-Jia ;

Yuan, Ru-Ming ;

Feng, Jia-Min ;

Zhang, Qian ;

Huang, Jing-Xin ;

Fu, Gang ;

Zheng, Ming-Sen ;

Ren, Bin ;

Dong, Quan-Feng .

CHEMISTRY OF MATERIALS, 2015, 27 (06) :2048-2055

[8] Self-Templated Formation of Interlaced Carbon Nanotubes Threaded Hollow Co3S4 Nanoboxes for High-Rate and Heat-Resistant Lithium-Sulfur Batteries [J].

Chen, Tao ;

Zhang, Zewen ;

Cheng, Baorui ;

Chen, Renpeng ;

Hu, Yi ;

Ma, Lianbo ;

Zhu, Guoyin ;

Liu, Jie ;

Jin, Zhong .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2017, 139 (36) :12710-12715

[9] Metallic and polar Co9S8 inlaid carbon hollow nanopolyhedra as efficient polysulfide mediator for lithium-sulfur batteries [J].

Chen, Tao ;

Ma, Lianbo ;

Cheng, Baorui ;

Chen, Renpeng ;

Hu, Yi ;

Zhu, Guoyin ;

Wang, Yanrong ;

Liang, Jia ;

Tie, Zuoxiu ;

Liu, Jie ;

Jin, Zhong .

NANO ENERGY, 2017, 38 :239-248

[10] A New Hydrophilic Binder Enabling Strongly Anchoring Polysulfides for High-Performance Sulfur Electrodes in Lithium-Sulfur Battery [J].

Chen, Wei ;

Lei, Tianyu ;

Qian, Tao ;

Lv, Weiqiang ;

He, Weidong ;

Wu, Chunyang ;

Liu, Xuejun ;

Liu, Jie ;

Chen, Bo ;

Yan, Chenglin ;

Xiong, Jie .

ADVANCED ENERGY MATERIALS, 2018, 8 (12)

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